SDS - Campbell Shadow Ultra PGR - 260201

COLIN CAMPBELL (CHEMICALS) PTY. LTD.

SAFETY DATA SHEET Date of Issue: 1 February 2026

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Section 1 - Identification of the Material and Supplier

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Section 2 - Hazards Identification

Statement of Hazardous Nature

This product is classified as: Xn, Harmful. Hazardous according to the criteria of SWA. Not a Dangerous Good according to Australian Dangerous Goods (ADG) Code, IATA or IMDG/IMSBC criteria.

• SUSMP Classification: S5
• ADG Classification: None allocated. Not a Dangerous Good according to Australian Dangerous Goods (ADG) Code, IATA or IMDG/IMSBC criteria.
• UN Number: None allocated

[Exclamation Mark GHS Hazard Symbol]

Ghs Signal Word: Warning

Acute Toxicity Inhalation Category 4

Hazard Statement:

• H332: Harmful if inhaled.

Prevention

• P102: Keep out of reach of children.
• P261: Avoid breathing dust/fumes/gas/mists/vapours/spray.
• P262: Do not get in eyes, on skin, or on clothing.
• P271: Use only outdoors or in a well-ventilated area.
• P280: Wear protective gloves/protective clothing/eye protection/face protection/hearing protection.

Response

• P312: Call a POISON CENTRE or doctor if you feel unwell.
• P352: Wash with plenty of soap and water.
• P301+P330+P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
• P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
• P370+P378: In case of fire, use carbon dioxide, dry chemical, foam, water fog.

Storage

• P410: Protect from sunlight.
• P402+P404: Store in a dry place. Store in a closed container.
• P403+P235: Store in a well-ventilated place. Keep cool.

Disposal

• P501: Dispose of contents and containers as specified on the registered la

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COLIN CAMPBELL (CHEMICALS) PTY. LTD.

SAFETY DATA SHEET Date of Issue: 1 February 2026

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Emergency Overview

• Physical Description & colour: Clear yellow liquid.
• Odour: No odour.
• Major Health Hazards: Harmful if inhaled.

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COLIN CAMPBELL (CHEMICALS) PTY. LTD.

SAFETY DATA SHEET Date of Issue: 12 December 2022

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Section 3 - Composition/information on Ingredients

This is a commercial product whose exact ratio of components may vary slightly. Minor quantities of other non hazardous ingredients are also possible.

The SWA TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5 day working week. The STEL (Short Term Exposure Limit) is an exposure value that may be equalled (but should not be exceeded) for no longer than 15 minutes and should not be repeated more than 4 times per day. There should be at least 60 minutes between successive exposures at the STEL. The term "peak "is used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.

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Section 4 - First Aid Measures

General Information:

You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all times. Have this SDS with you when you call.

• Inhalation: If symptoms of poisoning become evident, contact a Poisons Information Centre, or call a doctor at once. Remove source of contamination or move victim to fresh air. If breathing is difficult, oxygen may be beneficial if administered by trained personnel, preferably on a doctor's advice. DO NOT allow victim to move about unnecessarily. Symptoms of pulmonary oedema can be delayed up to 48 hours after exposure.
• Skin Contact: Irritation is unlikely. However, if irritation does occur, flush with lukewarm, gently flowing water for 5 minutes or until chemical is removed.
• Eye Contact: No effects expected. If irritation does occur, flush contaminated eye(s) with lukewarm, gently flowing water for 5 minutes or until the product is removed. Obtain medical advice if irritation becomes painful or lasts more than a few minutes. Take special care if exposed person is wearing contact lenses.
• Ingestion: If product is swallowed or gets in mouth, do NOT induce vomiting; wash mouth with water and give some water to drink. If symptoms develop, or if in doubt contact a Poisons Information Centre or a doctor.

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Section 5 - Fire Fighting Measures

• Fire and Explosion Hazards: The major hazard in fires is usually inhalation of heated and toxic or oxygen deficient (or both), fire gases. There is little risk of an explosion from this product if commercial quantities are involved in a fire. Violent steam generation or eruption may occur upon application of direct water stream on hot liquids. Vapours from this product are heavier than air and may accumulate in sumps, pits and other low-lying spaces, forming potentially explosive mixtures. They may also flash back considerable distances.
• Fire decomposition products from this product may be toxic if inhaled. Take appropriate protective measures.
• Extinguishing Media: In case of fire, use carbon dioxide, dry chemical, foam, water fog.
• Fire Fighting: When fighting fires involving significant quantities of this product, wear a splash suit complete with self contained breathing apparatus.
• Flash point: $94.4^\circ\text{C}$
• Upper Flammability Limit: No data.
• Lower Flammability Limit: No data.
• Autoignition temperature: No data.
• Flammability Class: Not flammable (GHS); C1 combustible (AS 1940)

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Section 6 - Accidental Release Measures

• Accidental release: In the event of a major spill, prevent spillage from entering drains or water courses. Wear full protective clothing including eye/face protection. All skin areas should be covered. See below under Personal Protection regarding Australian Standards relating to personal protective equipment. Suitable materials for protective clothing include Nitrile, butyl rubber, neoprene. Eye/face protective equipment should comprise as a minimum, protective goggles. If there is a significant chance that vapours or mists are likely to build up in the cleanup area, we recommend that you use a respirator. Usually, no respirator is necessary when using this product. However, if you

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COLIN CAMPBELL (CHEMICALS) PTY. LTD.

SAFETY DATA SHEET Date of Issue: 12 December 2022

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have any doubts consult the Australian Standard mentioned below (section 8). Stop leak if safe to do so, and contain spill. Absorb onto sand, vermiculite or other suitable absorbent material. If spill is too large or if absorbent material is not available, try to create a dike to stop material spreading or going into drains or waterways. Sweep up and shovel or collect recoverable product into labelled containers for recycling or salvage, and dispose of promptly. Recycle containers wherever possible after careful cleaning. Refer to product label for specific instructions. After spills, wash area preventing runoff from entering drains. If a significant quantity of material enters drains, advise emergency services. Full details regarding disposal of used containers, spillage and unused material may be found on the label. If there is any conflict between this SDS and the label, instructions on the label prevail. Ensure legality of disposal by consulting regulations prior to disposal. Thoroughly launder protective clothing before storage or re-use. Advise laundry of nature of contamination when sending contaminated clothing to laundry.

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Section 7 - Handling and Storage

• Handling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check Section 8 of this SDS for details of personal protective measures, and make sure that those measures are followed. The measures detailed below under "Storage" should be followed during handling in order to minimise risks to persons using the product in the workplace. Also, avoid contact or contamination of product with incompatible materials listed in Section 10.
• Storage: This product is a Scheduled Poison. Observe all relevant regulations regarding sale, transport and storage of this schedule of poison. Protect this product from light. Store in the closed original container in a dry, cool, well-ventilated area out of direct sunlight. Make sure that the product does not come into contact with substances listed under "Incompatibilities" in Section 10. Some liquid preparations settle or separate on standing and may require stirring before use. Check packaging - there may be further storage instructions on the label.

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Section 8 - Exposure Controls and Personal Protection

The following Australian Standards will provide general advice regarding safety clothing and equipment:

• Respiratory equipment: AS/NZS 1715
• Protective Gloves: AS 2161
• Occupational Protective Clothing: AS/NZS 4501 set 2008
• Industrial Eye Protection: AS1336 and AS/NZS 1337
• Occupational Protective Footwear: AS/NZS2210

Swa Exposure Limits

• TWA ($mg/m^3$): Exposure limits have not been established by SWA for any of the significant ingredients in this product.
• STEL ($mg/m^3$): Exposure limits have not been established by SWA for any of the significant ingredients in this product.

The ADI for Trinexapac-ethyl is set at $0.01\text{mg/kg/day}$. The corresponding NOEL is set at $1.4\text{mg/kg/day}$. ADI means Acceptable Daily Intake; NOEL means No-observable-effect-level. Data from Australian ADI List, June 2014.

No special equipment is usually needed when occasionally handling small quantities. The following instructions are for bulk handling or where regular exposure in an occupational setting occurs without proper containment systems.

• Ventilation: This product should only be used in a well ventilated area. If natural ventilation is inadequate, use of a fan is suggested.
• Eye Protection: Eye protection such as protective glasses or goggles is recommended when this product is being used.
• Skin Protection: The information at hand indicates that this product is not harmful and that normally no special skin protection is necessary. However, we suggest that you routinely avoid contact with all chemical products and that you wear suitable gloves (preferably elbow-length) when skin contact is likely.
• Protective Material Types: We suggest that protective clothing be made from the following materials: nitrile, butyl rubber, neoprene.
• Respirator: Usually, no respirator is necessary when using this product. However, if you have any doubts consult the Australian Standard mentioned above.

Safety deluge showers should, if practical, be provided near to where this product is being handled commercially.

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COLIN CAMPBELL (CHEMICALS) PTY. LTD.

SAFETY DATA SHEET Date of Issue: 12 December 2022

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Section 9 - Physical and Chemical Properties:

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Section 10 - Stability and Reactivity

• Reactivity: This product is unlikely to react or decompose under normal storage conditions. However, if you have any doubts, contact the supplier for advice on shelf life properties.
• Conditions to Avoid: Protect this product from light. Store in the closed original container in a dry, cool, well-ventilated area out of direct sunlight.
• Incompatibilities: No particular Incompatibilities.
• Fire Decomposition: Combustion forms carbon dioxide, and if incomplete, carbon monoxide and possibly smoke. Water is also formed. Irritating and toxic fumes. Carbon monoxide poisoning produces headache, weakness, nausea, dizziness, confusion, dimness of vision, disturbance of judgment, and unconsciousness followed by coma and death.
• Polymerisation: Polymerisation reactions are unlikely; they are not expected to occur.

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Section 11 - Toxicological Information

Local Effects:

• Target Organs: Trinexapac-Ethyl Technical: Liver, kidney, brain.

Acute Toxicity/irritation Studies (Finished Product):

• Acute Oral $\text{LD}_{50}$ (Rat): $> 3,129\text{ mg/kg}$
• Acute Dermal $\text{LD}_{50}$ (Rat): $> 5,000\text{ mg/kg}$
• Acute Inhalation $\text{LC}_{50}$ (Rat): $> 2.12\text{ mg/L}$ (4 hrs.)
• Eye Irritation: Minimally irritating
• Dermal Irritation: Non-irritating
• Dermal Sensitization: Not a skin sensitizer

Symptoms of Overexposure:

Symptoms of overexposure are headaches, dizziness, numbness, nausea, lack of coordination or other central nervous system effects.

Reproductive/developmental Effects:

• Trinexapac-Ethyl Technical: None observed.

Chronic/subchronic Effects:

• Trinexapac-Ethyl Technical: Liver, kidney and brain (dogs) effects at high doses ($>5,000\text{ ppm}$).

Carcinogenicity:

Trinexapac-Ethyl Technical: Slight increase in stomach tumours in male mice at high doses ($2,000\text{ ppm}$). Slight increase in fore stomach tumours in male rats at high doses ($20,000\text{ mg/kg/day}$). The U.S. EPA has classified Trinexapac-ethyl as "not likely to be carcinogenic to humans."

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COLIN CAMPBELL (CHEMICALS) PTY. LTD.

SAFETY DATA SHEET Date of Issue: 12 December 2022

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Classification of Hazardous Ingredients

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Potential Health Effects

Inhalation:

• Short term exposure: Available data shows that this product is harmful, but symptoms are not available. In addition product may be mildly irritating, although unlikely to cause anything more than mild transient discomfort.
• Long Term exposure: No data for health effects associated with long term inhalation.

Skin Contact:

• Short term exposure: Available data indicates that this product is not harmful. It should present no hazards in normal use. However product may be mildly irritating, but is unlikely to cause anything more than mild discomfort which should disappear once contact ceases.
• Long Term exposure: No data for health effects associated with long term skin exposure.

Eye Contact:

• Short term exposure: This product may be irritating to eyes, but is unlikely to cause anything more than mild transient discomfort.
• Long Term exposure: No data for health effects associated with long term eye exposure.

Ingestion:

• Short term exposure: Significant oral exposure is considered to be unlikely. However, this product may be mildly irritating to mucous membranes but is unlikely to cause anything more than mild transient discomfort.
• Long Term exposure: No data for health effects associated with long term ingestion.

Carcinogen Status:

• SWA: No significant ingredient is classified as carcinogenic by SWA.
• NTP: No significant ingredient is classified as carcinogenic by NTP.
• IARC: No significant ingredient is classified as carcinogenic by IARC.

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Section 12 - Ecological Information

This product is biodegradable. It will not accumulate in the soil or water or cause long term problems.

For Trinexapac-ethyl:

• Birds: $\text{LD}{50}$ mallard: $>2000\text{mg/kg}$ | $\text{LD}{50}$ bobwhite quail: $>2250\text{mg/kg}$
• Fish: $\text{LC}_{50}$ rainbow trout (Oncorhynchus mykiss): $68\text{mg/L}$
• $\text{LC}_{50}$ bluegill sunfish (Lepomis macrochirus): $130.1\text{mg/L}$
• Daphnia: $\text{EC}_{50} >142.5\text{mg/L}$

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Section 13 - Disposal Considerations

• Disposal: Special help is available for the disposal of Agricultural Chemicals. The product label will give general advice regarding disposal of small quantities, and how to cleanse containers. However, for help with the collection of unwanted rural chemicals, contact ChemClear and for help with the disposal of empty drums, contact DrumMuster where you will find contact details for your area.

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Section 14 - Transport Information

• UN Number: This product is not classified as a Dangerous Good by ADG, IATA or IMDG/IMSBC criteria. No special transport conditions are necessary unless required by other regulations.

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COLIN CAMPBELL (CHEMICALS) PTY. LTD.

SAFETY DATA SHEET Date of Issue: 12 December 2022

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Section 15 - Regulatory Information

• AICS: All of the significant ingredients in this formulation are compliant with NICNAS regulations. The following ingredient: Trinexapac-ethyl, is mentioned in the SUSMP.

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Section 16 - Other Information

This SDS contains only safety-related information. For other data see product literature.

Acronyms:

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THIS SDS SUMMARISES OUR BEST KNOWLEDGE OF THE HEALTH AND SAFETY HAZARD INFORMATION OF THE PRODUCT AND HOW TO SAFELY HANDLE AND USE THE PRODUCT IN THE WORKPLACE. EACH USER MUST REVIEW THIS SDS IN THE CONTEXT OF HOW THE PRODUCT WILL BE HANDLED AND USED IN THE WORKPLACE.

IF CLARIFICATION OR FURTHER INFORMATION IS NEEDED TO ENSURE THAT AN APPROPRIATE RISK ASSESSMENT CAN BE MADE, THE USER SHOULD CONTACT THIS COMPANY SO WE CAN ATTEMPT TO OBTAIN ADDITIONAL INFORMATION FROM OUR SUPPLIERS

OUR RESPONSIBILITY FOR PRODUCTS SOLD IS SUBJECT TO OUR STANDARD TERMS AND CONDITIONS, A COPY OF WHICH IS SENT TO OUR CUSTOMERS AND IS ALSO AVAILABLE ON REQUEST.

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