SDS - David Grays Mancozeb Fungicide - 250419

DAVID GRAY & CO. PTY LIMITED 2 Rawlinson Street O'CONNOR WA 6163

SAFETY DATA SHEET

PRODUCT NAME DAVID GRAYS MANCOZEB FUNGICIDE

1. Identification of the Material and Supplier

• Supplier name DAVID GRAY & CO PTY LIMITED
• Address 2 Rawlinson St, O'Connor, WA, 6961, AUSTRALIA
• Emergency (B/H)
• Web site
• Synonym(s) 50915 (12X125G) - MANUFACTURER'S CODE
• Use(s) FUNGICIDE
• SDS date 19 April 2021

2. Hazards Identification

CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA

Risk Phrases

• R43: May cause sensitisation by skin contact.
• R50: Very toxic to aquatic organisms.
• R63: Possible risk of harm to the unborn child.

Safety Phrases

• S2: Keep out of reach of children.
• S36/37: Wear suitable protective clothing and gloves.
• S46: If swallowed, contact a doctor or Poisons Information Centre immediately and show container or label.
• S51: Use only in well ventilated areas.

NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE

• UN Number None Allocated
• Transport Hazard Class None Allocated
• Packing Group None Allocated
• Hazchem Code None Allocated

3. Composition/ Information on Ingredients

4. First Aid Measures

• Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
• Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.
• Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.
• Ingestion For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). If swallowed, do not induce vomiting. Avoid giving alcohol.

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PRODUCT NAME DAVID GRAYS MANCOZEB FUNGICIDE

• Advice to doctor Treat symptomatically.
• First aid facilities Eye wash facilities and safety shower should be available.

5. Fire Fighting Measures

• Flammability Non flammable. May evolve toxic gases (nitrogen oxides, sulphur oxides, hydrogen sulphide, carbon oxides, hydrocarbons) when heated to decomposition. May evolve hydrogen sulphide and carbon disulphide when heated to decomposition.
• Fire and explosion Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas. May also evolve hydrogen sulphide and carbon disulphide when heated to decomposition.
• Extinguishing Use an extinguishing agent suitable for the surrounding fire.
• Hazchem code None allocated.

6. Accidental Release Measures

• Personal precautions Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel. Contact emergency services where appropriate.
• Environmental precautions Prevent product from entering drains and waterways.
• Methods of cleaning up Contain spillage, then collect and place in suitable containers for reuse or disposal. Avoid generating dust.
• References See Sections 8 and 13 for exposure controls and disposal.

7. Storage and Handling

• Storage Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequately labelled and tightly closed when not in use.
• Handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.

8. Exposure Controls / Personal Protection

• Exposure standards No exposure standard(s) allocated.
• Biological limits No biological limit allocated.
• Engineering controls Avoid inhalation. Use in well ventilated areas. Maintain dust levels below the recommended exposure standard.
• PPE
  • Eye / Face Wear dust-proof goggles.
  • Hands Wear PVC or rubber gloves.
  • Body When using large quantities or where heavy contamination is likely, wear coveralls.
  • Respiratory Wear a Class P1 (Particulate) respirator. Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
  • [Diagrams showing PPE icons: Eye/Face protection goggles, Gloves, Coveralls/Body protection, Respiratory protection]

9. Physical and Chemical Properties

• Appearance FINE YELLOW POWDER
• Odour SLIGHT ODOUR

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PRODUCT NAME DAVID GRAYS MANCOZEB FUNGICIDE

• Flammability NON FLAMMABLE
• Flash point NOT RELEVANT
• Boiling point NOT AVAILABLE
• Melting point NOT AVAILABLE
• Evaporation rate NOT AVAILABLE
• pH NOT AVAILABLE
• Vapour density NOT AVAILABLE
• Specific gravity NOT AVAILABLE
• Solubility (water) DISPERSIBLE
• Vapour pressure NOT AVAILABLE
• Upper explosion limit NOT RELEVANT
• Lower explosion limit NOT RELEVANT
• Decomposition temperature > 120°C
• Explosive properties NOT AVAILABLE
• Oxidising properties NOT AVAILABLE

10. Stability and Reactivity

• Chemical stability Stable under recommended conditions of storage.
• Conditions to avoid Avoid heat, sparks, open flames and other ignition sources.
• Material to avoid Incompatible with oxidising agents (e.g. hypochlorites), acids (e.g. nitric acid), heat, light and moisture. The manufacturer reports that this product is slightly corrosive to mild steel.
• Hazardous Decomposition Products May evolve toxic gases (nitrogen oxides, sulphur oxides, hydrogen sulphide, carbon oxides, hydrocarbons) when heated to decomposition.
• Hazardous Reactions Polymerization is not expected to occur.

11. Toxicological Information

• Health Hazard Summary May be harmful. This product has the potential to cause adverse health effects with over exposure. Use safe work practices to avoid eye or skin contact and inhalation. Allergic skin disorders may occur with prolonged periods of exposure.
• Eye Irritant. Contact may result in irritation, lacrimation, pain and redness.
• Inhalation Low irritant. Over exposure may result in irritation of the nose and throat, with coughing.
• Skin Irritant. Contact may result in irritation, redness and rash. May cause sensitisation by skin contact.
• Ingestion May be harmful. Ingestion may result in gastrointestinal irritation, nausea, vomiting, abdominal pain and diarrhoea.
• Toxicity data
  • MANCOZEB (8018-01-7)
    • LD50 (oral) 5000 mg/kg (rat)
    • LD50 (dermal) 5000 mg/kg (rabbit)

12. Ecological Information

• Toxicity Very toxic to aquatic organisms.
• Persistence and degradability No information provided.
• Bioaccumulative potential No information provided.
• Mobility in soil No information provided.
• Other adverse effects Prevent contamination of drains or waterways.

13. Disposal Considerations

• Waste disposal Ensure product is covered with moist soil to prevent dust generation and dispose of to approved Council landfill. Contact the manufacturer/supplier for additional information (if required).
• Legislation Dispose of in accordance with relevant local legislation.

14. Transport Information

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PRODUCT NAME DAVID GRAYS MANCOZEB FUNGICIDE

NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA

15. Regulatory Information

• Poison schedule Classified as a Schedule 5 (S5) Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP).
• Inventory Listing(s) AUSTRALIA: AICS (Australian Inventory of Chemical Substances) All components are listed on AICS, or are exempt.

16. Other Information

Additional information

controlsRESPIRATORS: In general the use of respirators should be limited and engineering employed to avoid exposure. If respiratory equipment must be worn ensure correct respirator selection and training is undertaken. Remember that some respirators may be extremely uncomfortable when used for long periods. The use of air powered or air supplied respirators should be considered where prolonged or repeated use is necessary.

WORKPLACE CONTROLS AND PRACTICES: Unless a less toxic chemical can be substituted for a hazardous substance, ENGINEERING CONTROLS are the most effective way of reducing exposure. The best protection is to enclose operations and/or provide local exhaust ventilation at the site of chemical release. Isolating operations can also reduce exposure. Using respirators or protective equipment is less effective than the controls mentioned above, but is sometimes necessary.

PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as form of product, method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made.

HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: form of product; frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.

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PRODUCT NAME DAVID GRAYS MANCOZEB FUNGICIDE

• Abbreviations

  • ACGIH: American Conference of Governmental Industrial Hygienists
  • CAS #: Chemical Abstract Service number - used to uniquely identify chemical compounds
  • CNS: Central Nervous System
  • EC No.: EC No - European Community Number
  • EMS: Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous Goods)
  • GHS: Globally Harmonized System
  • GTEPG: Group Text Emergency Procedure Guide
  • IARC: International Agency for Research on Cancer
  • LC50: Lethal Concentration, 50% / Median Lethal Concentration
  • LD50: Lethal Dose, 50% / Median Lethal Dose
  • mg/m³: Milligrams per Cubic Metre
  • OEL: Occupational Exposure Limit
  • pH: relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline).
  • ppm: Parts Per Million
  • STEL: Short-Term Exposure Limit
  • STOT-RE: Specific target organ toxicity (repeated exposure)
  • STOT-SE: Specific target organ toxicity (single exposure)
  • SUSMP: Standard for the Uniform Scheduling of Medicines and Poisons
  • SWA: Safe Work Australia
  • TLV: Threshold Limit Value
  • TWA: Time Weighted Average

• Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the product and serves as their Safety Data Sheet ('SDS').

  It is based on information concerning the product which has been provided to RMT by the manufacturer, importer or supplier or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer, importer or supplier.

  While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS.

• Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005

[ End of SDS ]

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