SDS - Searles Trifend Garden Spray - 251001
Applies to Trifend | Garden Spray | Insecticide, Fungicide & Miticide
Document contents
Text extracted from the source document for accessibility and reference. Always consult the original safety data sheet above for the authoritative version.
Product Name: Searles® Trifend® Garden Spray Page: 1 of 5 This revision issued: October, 2025
SAFETY DATA SHEET Issued by: J.C. & A.T. Searle Pty Ltd Phone: Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Section 1 - Identification of the Material and Supplier
J.C. & A.T. Searle Pty Ltd 4914 D’aguilar Highway (PO Box 183) Phone: (BH)
Chemical nature: Water solution of ingredients at Ready-To-Use concentrations. Trade Name: Searles® Trifend® Garden Spray Product Code: TRF200 and TRF500 Product Use: Horticultural insecticide, fungicide and miticide for use as described on the product label. Creation Date: June, 2012 This version issued: October, 2025 and is valid for 5 years from this date. Poisons Information Centre: Phone 13 1126 from anywhere in Australia
Section 2 - Hazards Identification
Statement of Hazardous Nature SUSMP Classification: S5 ADG Classification: None allocated. Not a Dangerous Good under the ADG Code. UN Number: None allocated
GHS Signal word: WARNING. Reproductive toxicity – category 2 Hazardous to aquatic environment Short term/Acute Category 3
HAZARD STATEMENT: H361f: Suspected of damaging the unborn child. H402: Harmful to aquatic life.
PREVENTION P102: Keep out of reach of children. P262: Do not get in eyes, on skin, or on clothing. P273: Avoid release to the environment. P281: Use personal protective equipment as required.
RESPONSE P337: If eye irritation persists: seek medical attention. P353: Rinse skin or shower with water. P301+P330+P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P370+P378: Not combustible. Use extinguishing media suited to burning materials.
STORAGE P402+P404: Store in a dry place. Store in a closed container. P403+P235: Store in a well-ventilated place. Keep cool.
DISPOSAL P501: Dispose of contents and containers as specified on the registered label.
Emergency Overview Physical Description & Colour: Milky white liquid. Odour: Mild odour. Major Health Hazards: no suspected of damaging the unborn child. [Sic - OCR error in source text]
[Skull and crossbones hazard symbol]
SAFETY DATA SHEET Issued by: J.C. & A.T. Searle Pty Ltd Phone: Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: Searles® Trifend® Garden Spray Page: 2 of 5 This revision issued: October, 2025
Section 3 - Composition/information on Ingredients
| Ingredients | CAS No | Conc,% | TWA ($mg/m^3$) | STEL ($mg/m^3$) |
|---|---|---|---|---|
| Tau-fluvalinate | 102851-06-9 | 9.6g/L | not set | not set |
| Myclobutanil | 88671-89-0 | 4.4g/L | not set | not set |
| Other non hazardous ingredients | secret | to 100 | not set | not set |
This is a commercial product whose exact ratio of components may vary slightly. Minor quantities of other non hazardous ingredients are also possible.
The SWA TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5 day working week. The STEL (Short Term Exposure Limit) is an exposure value that may be equalled (but should not be exceeded) for no longer than 15 minutes and should not be repeated more than 4 times per day. There should be at least 60 minutes between successive exposures at the STEL. The term "peak" is used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.
Section 4 - First Aid Measures
General Information: You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all times. Have this SDS with you when you call.
Inhalation: First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor. Skin Contact: Irritation is unlikely. However, if irritation does occur, flush with lukewarm, gently flowing water for 5 minutes or until chemical is removed. Eye Contact: No effects expected. If irritation does occur, flush contaminated eye(s) with lukewarm, gently flowing water for 5 minutes or until the product is removed. Obtain medical advice if irritation becomes painful or lasts more than a few minutes. Take special care if exposed person is wearing contact lenses. Ingestion: If product is swallowed or gets in mouth, do NOT induce vomiting; wash mouth with water and give some water to drink. If symptoms develop, or if in doubt contact a Poisons Information Centre or a doctor.
Section 5 - Fire Fighting Measures
Fire and Explosion Hazards: There is no risk of an explosion from this product under normal circumstances if it is involved in a fire. This product is likely to decompose only after heating to dryness, followed by further strong heating. Fire decomposition products from this product are likely to be toxic and corrosive if inhaled. Take appropriate protective measures. Extinguishing Media: Not Combustible. Use extinguishing media suited to burning materials. Fire Fighting: If a significant quantity of this product is involved in a fire, call the fire brigade. Flammability Class: Does not burn.
Section 6 - Accidental Release Measures
Accidental release: This product is sold in small packages, and the accidental release from one of these is not usually a cause for concern. For minor spills, clean up, rinsing to sewer and put empty container in garbage. Although no special protective clothing is normally necessary because of occasional minor contact with this product, it is good practice to wear impermeable gloves when handling chemical products. In the event of a major spill, prevent spillage from entering drains or water courses and call emergency services.
Section 7 - Handling and Storage
Handling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check Section 8 of this SDS for details of personal protective measures, and make sure that those measures are followed. The measures detailed below under "Storage" should be followed during handling in order to minimise risks to persons using the product in the workplace. Also, avoid contact or contamination of product with incompatible materials listed in Section 10. Storage: This product is a Scheduled Poison. Observe all relevant regulations regarding sale, transport and storage of this schedule of poison. Protect this product from light. Store in the closed original container in a dry, cool, well-ventilated area out of direct sunlight. Make sure that the product does not come into contact with substances listed under "Incompatibilities" in Section 10. Some liquid preparations settle or separate on standing and may require stirring before use. Check packaging - there may be further storage instructions on the label.
SAFETY DATA SHEET Issued by: J.C. & A.T. Searle Pty Ltd Phone: Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: Searles® Trifend® Garden Spray Page: 3 of 5 This revision issued: October, 2025
Section 8 - Exposure Controls and Personal Protection
The following Australian Standards will provide general advice regarding safety clothing and equipment: Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Occupational Protective Clothing: AS/NZS 4501 set 2008, Industrial Eye Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210.
| SWA Exposure Limits | TWA ($mg/m^3$) | STEL ($mg/m^3$) |
|---|---|---|
| Exposure limits have not been established by SWA for any of the significant ingredients in this product. |
The ADI for Myclobutanil is set at 0.03mg/kg/day. The corresponding NOEL is set at 2.6mg/kg/day. ADI means Acceptable Daily Intake; NOEL means No-observable-effect-level. Data from Australian ADI List, June 2014.
No special equipment is usually needed when occasionally handling small quantities. The following instructions are for bulk handling or where regular exposure in an occupational setting occurs without proper containment systems. Ventilation: No special ventilation requirements are normally necessary for this product. However make sure that the work environment remains clean and that vapours and mists are minimised. Eye Protection: Eye protection such as protective glasses or goggles is recommended when this product is being used. Skin Protection: The information at hand indicates that this product is not harmful and that normally no special skin protection is necessary. However, we suggest that you routinely avoid contact with all chemical products and that you wear suitable gloves (preferably elbow-length) when skin contact is likely. Protective Material Types: We suggest that protective clothing be made from the following materials: rubber, PVC. Respirator: Usually, no respirator is necessary when using this product. However, if you have any doubts consult the Australian Standard mentioned above.
Section 9 - Physical and Chemical Properties:
Physical Description & colour: Milky white liquid. Odour: Mild odour. Boiling Point: Approximately 100°C at 100kPa. Flash point: Does not burn. Upper Flammability Limit: Does not burn. Lower Flammability Limit: Does not burn. Autoignition temperature: Not applicable - does not burn. Freezing/Melting Point: Approximately 0°C. Volatiles: Water component. Vapour Pressure: 2.37 kPa at 20°C (water vapour pressure). Vapour Density: No data. Specific Gravity: 1.01-1.02 Water Solubility: Completely soluble in water. pH: No data. Expected to be neutral. Volatility: No data. Odour Threshold: No data. Evaporation Rate: No data. Coeff Oil/water Distribution: No data Particle Characteristics: Not applicable to liquids.
Section 10 – Stability and Reactivity
Reactivity: This product is unlikely to react or decompose under normal storage conditions. However, if you have any doubts, contact the supplier for advice on shelf life properties. Conditions to Avoid: Protect this product from light. Store in the closed original container in a dry, cool, well-ventilated area out of direct sunlight. Incompatibilities: No particular Incompatibilities. Fire Decomposition: This product is likely to decompose only after heating to dryness, followed by further strong heating. Combustion forms carbon dioxide, and if incomplete, carbon monoxide. Water is also formed. May form nitrogen and its compounds, and under some circumstances, oxides of nitrogen. Occasionally hydrogen cyanide gas in reducing atmospheres. May form hydrogen fluoride gas and other compounds of fluorine. Carbon monoxide poisoning produces headache, weakness, nausea, dizziness, confusion, dimness of vision, disturbance of judgment, and unconsciousness followed by coma and death. Polymerisation: This product will not undergo polymerisation reactions.
SAFETY DATA SHEET Issued by: J.C. & A.T. Searle Pty Ltd Phone: Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: Searles® Trifend® Garden Spray Page: 4 of 5 This revision issued: October, 2025
Section 11 - Toxicological Information
Local Effects: Target Organs: There is no data to hand indicating any particular target organs. Myclobutanil is a SWA Class 3 Reproductive risk.
Classification of Hazardous Ingredients Ingredient Health Hazard Statement Codes Tau-fluvalinate H302, H315, H410
- Acute toxicity – category 4
- Skin irritation – category 2
- Hazardous to the aquatic environment (acute) – category 1
- Hazardous to the aquatic environment (chronic) – category 1
Myclobutanil H361d, H302, H319, H411
- Reproductive toxicity – category 2
- Acute toxicity – category 4
- Eye irritation – category 2
- Hazardous to the aquatic environment (chronic) – category 2
Tau-fluvalinate is very toxic to aquatic organisms (see below), but is present only in small concentrations in this product. LC₅₀ Fish: rainbow trout (Oncorhynchus mykiss): 0.0027mg/L EC₅₀ Daphnia: 0.001mg/L
Potential Health Effects
Inhalation: Short Term Exposure: Available data indicates that this product is not harmful. In addition product is unlikely to cause any discomfort or irritation. Long Term Exposure: This product is carcinogenic by inhalation exposure.
Skin Contact: Short Term Exposure: Available data indicates that this product is not harmful. It should present no hazards in normal use. However product may be mildly irritating, but is unlikely to cause anything more than mild discomfort which should disappear once contact ceases. Long Term Exposure: No data for health effects associated with long term skin exposure.
Eye Contact: Short Term Exposure: This product may be irritating to eyes, but is unlikely to cause anything more than mild transient discomfort. Long Term Exposure: No data for health effects associated with long term eye exposure.
Ingestion: Short Term Exposure: Significant oral exposure is considered to be unlikely. However, this product may be irritating to mucous membranes but is unlikely to cause anything more than transient discomfort. Long Term Exposure: No data for health effects associated with long term ingestion.
Carcinogen Status: SWA: No significant ingredient is classified as carcinogenic by SWA. NTP: No significant ingredient is classified as carcinogenic by NTP. IARC: No significant ingredient is classified as carcinogenic by IARC.
Section 12 - Ecological Information
This product is harmful to aquatic organisms. Insufficient data to be sure of biodegradability status.
Section 13 - Disposal Considerations
Disposal: Dispose of small quantities and empty containers by wrapping with paper and putting in garbage. For larger quantities, if recycling or reclaiming is not possible, use a commercial waste disposal service.
SAFETY DATA SHEET Issued by: J.C. & A.T. Searle Pty Ltd Phone: Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: Searles® Trifend® Garden Spray Page: 5 of 5 This revision issued: October, 2025
Section 14 - Transport Information
UN Number: This product is not classified as a Dangerous Good by ADG, IATA or IMDG/IMSBC criteria. No special transport conditions are necessary unless required by other regulations.
Section 15 - Regulatory Information
AIIC: All of the significant ingredients in this formulation are compliant with AICIS regulations. The following ingredients: Tau-fluvalinate, Myclobutanil, are mentioned in the SUSMP.
Section 16 - Other Information
This SDS contains only safety-related information. For other data see product literature.
Acronyms:
| ADG Code | Australian Code for the Transport of Dangerous Goods by Road and Rail ($7^\text{th}$ edition) |
| AIIC | Australian Inventory of Industrial Chemicals |
| SWA | Safe Work Australia, formerly ASCC and NOHSC |
| CAS number | Chemical Abstracts Service Registry Number |
| IARC | International Agency for Research on Cancer |
| NTP | National Toxicology Program (USA) |
| SUSMP | Standard for the Uniform Scheduling of Medicines & Poisons |
| UN Number | United Nations Number |
THIS SDS SUMMARISES OUR BEST KNOWLEDGE OF THE HEALTH AND SAFETY HAZARD INFORMATION OF THE PRODUCT AND HOW TO SAFELY HANDLE AND USE THE PRODUCT IN THE WORKPLACE. EACH USER MUST REVIEW THIS SDS IN THE CONTEXT OF HOW THE PRODUCT WILL BE HANDLED AND USED IN THE WORKPLACE.
IF CLARIFICATION OR FURTHER INFORMATION IS NEEDED TO ENSURE THAT AN APPROPRIATE RISK ASSESSMENT CAN BE MADE, THE USER SHOULD CONTACT THIS COMPANY SO WE CAN ATTEMPT TO OBTAIN ADDITIONAL INFORMATION FROM OUR SUPPLIERS
OUR RESPONSIBILITY FOR PRODUCTS SOLD IS SUBJECT TO OUR STANDARD TERMS AND CONDITIONS, A COPY OF WHICH IS SENT TO OUR CUSTOMERS AND IS ALSO AVAILABLE ON REQUEST.
Please read all labels carefully before using product.
This SDS is prepared in accord with the SWA document “Preparation of Safety Data Sheets for Hazardous Chemicals - Code of Practice” (July 2020) and GHS Revision 7
Copyright © Kilford & Kilford Pty Ltd, October, 2025.
SAFETY DATA SHEET Issued by: J.C. & A.T. Searle Pty Ltd Phone: Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)