SDS - Envu Dedicate Forte Stressgard Turf Fungicide - 241106
Applies to Dedicate FORTE Stressgard | Turf Fungicide
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SAFETY DATA SHEET
DEDICATE FORTE STRESSGARD TURF FUNGICIDE
Version: 2.0 Revision Date: 06.11.2024 SDS Number: 11264709-00003 Date of last issue: 19.12.2023 Date of first issue: 27.10.2023
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Section 1: Identification
- Product name: DEDICATE FORTE STRESSGARD TURF FUNGICIDE
- Product code: Article/SKU: 87291316 UVP: 84962201 Specification: 102000031480
Manufacturer or Supplier's Details
Company: 2022 Environmental Science AU Pty Ltd
Address: Suite 2.06, Level 2, 737 Burwood Road Hawthorn East, Australia 3123
Emergency telephone number:
Recommended Use of the Chemical and Restrictions on Use
- Recommended use: Fungicide
- Restrictions on use: See product label for restrictions.
Section 2. Hazards Identification
Ghs Classification
- Reproductive toxicity: Category 2
Ghs Label Elements
Hazard pictograms: [Exclamation mark / Health hazard pictogram]
Signal word: Warning
Hazard statements: H361d Suspected of damaging the unborn child.
Precautionary statements:
Prevention: P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
SAFETY DATA SHEET
DEDICATE FORTE STRESSGARD TURF FUNGICIDE
Version: 2.0 Revision Date: 06.11.2024 SDS Number: 11264709-00003 Date of last issue: 19.12.2023 Date of first issue: 27.10.2023
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Response: P308 + P313 IF exposed or concerned: Get medical advice/ attention.
Storage: P405 Store locked up.
Disposal: P501 Dispose of contents/ container to an approved waste disposal plant.
Other Hazards Which Do Not Result in Classification
None known.
Section 3. Composition/information on Ingredients
- Substance / Mixture: Mixture
- Chemical nature: Suspension concentrate (=flowable concentrate)(SC)
Components
| Chemical name | CAS-No. | Concentration (% w/w) |
|---|---|---|
| Tebuconazole | 107534-96-3 | >= 10 -< 30 |
| Glycerine | 56-81-5 | >= 10 -< 30 |
| Alcohols, C16-18 and C18-unsatd., ethoxylated | 68920-66-1 | < 10 |
| Alkylnaphthalenesulfonic acid, polymer with formaldehyde, sodium salt | 68425-94-5 | < 10 |
| Reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H-isothiazol-3-one [EC no. 220-239-6] (3:1) | 55965-84-9 | >= 0.06 -< 0.1 |
Alternative Cas Numbers for Some Regions
| Chemical name | Alternative CAS Number(s) |
|---|---|
| Reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H-isothiazol-3-one [EC no. 220-239-6] (3:1) | 2682-20-4, 26172-55-4 |
Section 4. First Aid Measures
- General advice: In the case of accident or if you feel unwell, seek medical advice immediately. When symptoms persist or in all cases of doubt seek medical advice.
- If inhaled: If inhaled, remove to fresh air. Get medical attention.
SAFETY DATA SHEET
DEDICATE FORTE STRESSGARD TURF FUNGICIDE
Version: 2.0 Revision Date: 06.11.2024 SDS Number: 11264709-00003 Date of last issue: 19.12.2023 Date of first issue: 27.10.2023
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- In case of skin contact: In case of contact, immediately flush skin with soap and plenty of water. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
- In case of eye contact: Flush eyes with water as a precaution. Get medical attention if irritation develops and persists.
- If swallowed: If swallowed, DO NOT induce vomiting. Get medical attention. Rinse mouth thoroughly with water.
- Most important symptoms and effects, both acute and delayed: No symptoms known or expected. Suspected of damaging the unborn child.
- Protection of first-aiders: First Aid responders should pay attention to self-protection, and use the recommended personal protective equipment when the potential for exposure exists (see section 8).
- Notes to physician: Treat symptomatically. Gastric lavage is not normally required. However, if a significant amount (more than a mouthful) has been ingested, administer activated charcoal and sodium sulphate. Appropriate supportive and symptomatic treatment as indicated by the patient's condition is recommended.
Section 5. Firefighting Measures
- Suitable extinguishing media: Water spray Alcohol-resistant foam Carbon dioxide (CO2) Dry chemical
- Unsuitable extinguishing media: High volume water jet
- Specific hazards during firefighting: Vapours may form explosive mixtures with air. Exposure to combustion products may be a hazard to health.
- Hazardous combustion products: Nitrogen oxides (NOx) Chlorine compounds Carbon oxides Sulphur oxides Metal oxides
SAFETY DATA SHEET
DEDICATE FORTE STRESSGARD TURF FUNGICIDE
Version: 2.0 Revision Date: 06.11.2024 SDS Number: 11264709-00003 Date of last issue: 19.12.2023 Date of first issue: 27.10.2023
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- Specific extinguishing methods: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Use water spray to cool unopened containers. Remove undamaged containers from fire area if it is safe to do so. Evacuate area.
- Special protective equipment for firefighters: In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment.
- Hazchem Code: •3Z
Section 6. Accidental Release Measures
- Personal precautions, protective equipment and emergency procedures: Use personal protective equipment. Follow safe handling advice (see section 7) and personal protective equipment recommendations (see section 8).
- Environmental precautions: Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Prevent spreading over a wide area (e.g. by containment or oil barriers). Retain and dispose of contaminated wash water. Local authorities should be advised if significant spillages cannot be contained.
- Methods and materials for containment and cleaning up: Soak up with inert absorbent material. For large spills, provide dyking or other appropriate containment to keep material from spreading. If dyked material can be pumped, store recovered material in appropriate container. Clean up remaining materials from spill with suitable absorbent. Local or national regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which regulations are applicable. Sections 13 and 15 of this SDS provide information regarding certain local or national requirements.
Section 7. Handling and Storage
- Technical measures: See Engineering measures under EXPOSURE CONTROLS/PERSONAL PROTECTION section.
- Local/Total ventilation: Use only with adequate ventilation.
SAFETY DATA SHEET
DEDICATE FORTE STRESSGARD TURF FUNGICIDE
Version: 2.0 Revision Date: 06.11.2024 SDS Number: 11264709-00003 Date of last issue: 19.12.2023 Date of first issue: 27.10.2023
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- Advice on safe handling: Avoid inhalation of vapour or mist. Do not swallow. Avoid contact with eyes. Avoid prolonged or repeated contact with skin. Handle in accordance with good industrial hygiene and safety practice, based on the results of the workplace exposure assessment Take care to prevent spills, waste and minimize release to the environment.
- Hygiene measures: If exposure to chemical is likely during typical use, provide eye flushing systems and safety showers close to the working place. When using do not eat, drink or smoke. Wash contaminated clothing before re-use.
- Conditions for safe storage: Keep in properly labelled containers. Store locked up. Store in accordance with the particular national regulations.
- Materials to avoid: Do not store with the following product types: Strong oxidizing agents
Section 8. Exposure Controls/personal Protection
Components with Workplace Control Parameters
| Components | CAS-No. | Value type (Form of exposure) | Control parameters / Permissible concentration | Basis |
|---|---|---|---|---|
| Glycerine | 56-81-5 | TWA (Mist) | 10 mg/m3 | AU OEL |
- Engineering measures: Ensure adequate ventilation, especially in confined areas. Minimize workplace exposure concentrations.
Personal Protective Equipment
- Respiratory protection: If adequate local exhaust ventilation is not available or exposure assessment demonstrates exposures outside the recommended guidelines, use respiratory protection.
- Filter type: Combined particulates and organic vapour type
- Hand protection:
- Material: Nitrile rubber
- Break through time: 480 min
- Glove thickness: 0.4 mm
- Protective index: Class 6
SAFETY DATA SHEET
DEDICATE FORTE STRESSGARD TURF FUNGICIDE
Version: 2.0 Revision Date: 06.11.2024 SDS Number: 11264709-00003 Date of last issue: 19.12.2023 Date of first issue: 27.10.2023
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- Remarks: Choose gloves to protect hands against chemicals depending on the concentration and quantity of the hazardous substance and specific to place of work. For special applications, we recommend clarifying the resistance to chemicals of the aforementioned protective gloves with the glove manufacturer. Wash hands before breaks and at the end of workday.
- Eye protection: Wear the following personal protective equipment: Safety glasses
- Skin and body protection: Select appropriate protective clothing based on chemical resistance data and an assessment of the local exposure potential. Skin contact must be avoided by using impervious protective clothing (gloves, aprons, boots, etc).
Section 9. Physical and Chemical Properties
- Appearance: suspension
- Colour: dark green
- Odour: chalk-like
- Odour Threshold: No data available
- pH: ca. 9 Concentration: 100 %
- Melting point/freezing point: No data available
- Initial boiling point and boiling range: No data available
- Flash point: > 93.3 °C Method: closed cup
- Evaporation rate: No data available
- Flammability (solid, gas): Not applicable
- Flammability (liquids): No data available
SAFETY DATA SHEET
DEDICATE FORTE STRESSGARD TURF FUNGICIDE
Version: 2.0 Revision Date: 06.11.2024 SDS Number: 11264709-00003 Date of last issue: 19.12.2023 Date of first issue: 27.10.2023
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- Upper explosion limit / Upper flammability limit: No data available
- Lower explosion limit / Lower flammability limit: No data available
- Vapour pressure: No data available
- Relative vapour density: No data available
- Density: ca. 1.13 g/cm³ (20 °C)
- Solubility(ies):
- Water solubility: dispersible
- Partition coefficient: n-octanol/water: Not applicable
- Auto-ignition temperature: No data available
- Decomposition temperature: No data available
- Viscosity:
- Viscosity, dynamic: 600,000 - 1,100,000 mPa.s (25 °C)
- Viscosity, kinematic: No data available
- Explosive properties: Not explosive
- Oxidizing properties: The substance or mixture is not classified as oxidizing.
- Particle characteristics:
- Particle size: <= 3 µm <= 5 µm
Section 10. Stability and Reactivity
- Reactivity: Not classified as a reactivity hazard.
- Chemical stability: Stable under normal conditions.
- Possibility of hazardous reactions: Vapours may form explosive mixture with air. Can react with strong oxidizing agents.
- Conditions to avoid: None known.
- Incompatible materials: Oxidizing agents
SAFETY DATA SHEET
DEDICATE FORTE STRESSGARD TURF FUNGICIDE
Version: 2.0 Revision Date: 06.11.2024 SDS Number: 11264709-00003 Date of last issue: 19.12.2023 Date of first issue: 27.10.2023
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- Hazardous decomposition products: No hazardous decomposition products are known.
Section 11. Toxicological Information
- Exposure routes: Inhalation Skin contact Ingestion Eye contact
Acute Toxicity
Not classified based on available information.
Product:
- Acute oral toxicity: Acute toxicity estimate: > 2,000 mg/kg Method: Calculation method
Components:
Tebuconazole:
- Acute oral toxicity: LD50 (Rat, female): 1,700 mg/kg
- Acute inhalation toxicity: LC50 (Rat): > 2.118 mg/l Exposure time: 4 h Test atmosphere: dust/mist
- Acute dermal toxicity: LD50 (Rat): > 5,000 mg/kg
Glycerine:
- Acute oral toxicity: LD50 (Rat): > 5,000 mg/kg
- Acute dermal toxicity: LD50 (Guinea pig): > 5,000 mg/kg
Alcohols, C16-18 and C18-unsatd., ethoxylated:
- Acute oral toxicity: LD50 (Rat): > 2,000 mg/kg Remarks: Based on data from similar materials
Alkylnaphthalenesulfonic acid, polymer with formaldehyde, sodium salt:
- Acute oral toxicity: LD50 (Rat): > 4,500 mg/kg
Reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H-isothiazol-3-one [EC no. 220-239-6] (3:1):
- Acute oral toxicity: LD50 (Rat): 64 mg/kg
- Acute inhalation toxicity: LC50 (Rat): 0.171 mg/l Exposure time: 4 h Test atmosphere: dust/mist
SAFETY DATA SHEET
DEDICATE FORTE STRESSGARD TURF FUNGICIDE
Version: 2.0 Revision Date: 06.11.2024 SDS Number: 11264709-00003 Date of last issue: 19.12.2023 Date of first issue: 27.10.2023
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- Assessment: Corrosive to the respiratory tract.
- Acute dermal toxicity: LD50 (Rabbit): 87.12 mg/kg
Skin Corrosion/irritation
Not classified based on available information.
Product:
- Species: Rabbit
- Method: OECD Test Guideline 404
- Result: No skin irritation
Components:
Tebuconazole:
- Species: Rabbit
- Method: OECD Test Guideline 404
- Result: No skin irritation
Glycerine:
- Species: Rabbit
- Result: No skin irritation
Alcohols, C16-18 and C18-unsatd., ethoxylated:
- Species: Rabbit
- Method: OECD Test Guideline 404
- Result: No skin irritation
- Remarks: Based on data from similar materials
Reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H-isothiazol-3-one [EC no. 220-239-6] (3:1):
- Species: Rabbit
- Method: OECD Test Guideline 404
- Result: Corrosive after 1 to 4 hours of exposure
Serious Eye Damage/eye Irritation
Not classified based on available information.
Product:
- Species: Rabbit
- Result: No eye irritation
- Method: OECD Test Guideline 405
SAFETY DATA SHEET
DEDICATE FORTE STRESSGARD TURF FUNGICIDE
Version: 2.0 Revision Date: 06.11.2024 SDS Number: 11264709-00003 Date of last issue: 19.12.2023 Date of first issue: 27.10.2023
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Components:
Tebuconazole:
- Species: Rabbit
- Result: No eye irritation
Glycerine:
- Species: Rabbit
- Result: No eye irritation
Alcohols, C16-18 and C18-unsatd., ethoxylated:
- Result: Irritation to eyes, reversing within 7 days
Alkylnaphthalenesulfonic acid, polymer with formaldehyde, sodium salt:
- Result: Irritation to eyes, reversing within 21 days
Reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H-isothiazol-3-one [EC no. 220-239-6] (3:1):
- Result: Irreversible effects on the eye
- Remarks: Based on skin corrosivity.
Respiratory or Skin Sensitisation
- Skin sensitisation: Not classified based on available information.
- Respiratory sensitisation: Not classified based on available information.
Product:
- Species: Guinea pig
- Method: OECD Test Guideline 406
- Result: Does not cause skin sensitisation.
Components:
Tebuconazole:
- Test Type: Maximisation Test
- Exposure routes: Skin contact
- Species: Guinea pig
- Method: OECD Test Guideline 406
- Result: negative
Reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H-isothiazol-3-one [EC no. 220-239-6] (3:1):
- Test Type: Buehler Test
SAFETY DATA SHEET
DEDICATE FORTE STRESSGARD TURF FUNGICIDE
Version: 2.0 Revision Date: 06.11.2024 SDS Number: 11264709-00003 Date of last issue: 19.12.2023 Date of first issue: 27.10.2023
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- Exposure routes: Skin contact
- Species: Guinea pig
- Result: positive
- Assessment: Probability or evidence of high skin sensitisation rate in humans
Chronic Toxicity
Germ Cell Mutagenicity
Not classified based on available information.
Components:
Tebuconazole:
Genotoxicity in vitro: Test Type: Bacterial reverse mutation assay (AMES) Method: OECD Test Guideline 471 Result: negative
Test Type: In vitro mammalian cell gene mutation test Method: OECD Test Guideline 476 Result: negative
Test Type: Chromosome aberration test in vitro Method: OECD Test Guideline 473 Result: negative
Glycerine:
Genotoxicity in vitro: Test Type: In vitro mammalian cell gene mutation test Result: negative
Test Type: Bacterial reverse mutation assay (AMES) Result: negative
Test Type: Chromosome aberration test in vitro Result: negative
Test Type: DNA damage and repair, unscheduled DNA synthesis in mammalian cells (in vitro) Result: negative
Carcinogenicity
Not classified based on available information.
Components:
Tebuconazole:
- Species: Rat
- Application Route: Ingestion
- Exposure time: 2 y
SAFETY DATA SHEET
DEDICATE FORTE STRESSGARD TURF FUNGICIDE
Version: 2.0 Revision Date: 06.11.2024 SDS Number: 11264709-00003 Date of last issue: 19.12.2023 Date of first issue: 27.10.2023
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- Result: negative
Glycerine:
- Species: Rat
- Application Route: Ingestion
- Exposure time: 2 Years
- Result: negative
Reproductive Toxicity
Suspected of damaging the unborn child.
Components:
Tebuconazole:
- Effects on fertility: Test Type: Two-generation reproduction toxicity study Species: Rat Application Route: Ingestion Result: negative
- Effects on foetal development: Test Type: Two-generation reproduction toxicity study Species: Rat Application Route: Ingestion Method: OECD Test Guideline 414 Result: positive
- Reproductive toxicity - Assessment: Some evidence of adverse effects on development, based on animal experiments.
Glycerine:
- Effects on fertility: Test Type: Two-generation reproduction toxicity study Species: Rat Application Route: Ingestion Result: negative
- Effects on foetal development: Test Type: Embryo-foetal development Species: Rat Application Route: Ingestion Result: negative
Stot - Single Exposure
Not classified based on available information.
Stot - Repeated Exposure
Not classified based on available information.
Components:
Tebuconazole:
- Assessment: No significant health effects observed in animals at concentra-
SAFETY DATA SHEET
DEDICATE FORTE STRESSGARD TURF FUNGICIDE
Version: 2.0 Revision Date: 06.11.2024 SDS Number: 11264709-00003 Date of last issue: 19.12.2023 Date of first issue: 27.10.2023
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tions of 100 mg/kg bw or less.
Repeated Dose Toxicity
Components:
Tebuconazole:
- Species: Dog
- NOAEL: 3 mg/kg
- LOAEL: 4.4 mg/kg
- Application Route: Ingestion
- Exposure time: 1 yr
- Method: OECD Test Guideline 452
Glycerine:
Species: Rat
NOAEL: 0.167 mg/l
LOAEL: 0.622 mg/l
Application Route: inhalation (dust/mist/fume)
Exposure time: 13 Weeks
Species: Rat
NOAEL: 8,000 - 10,000 mg/kg
Application Route: Ingestion
Exposure time: 2 yr
Species: Rabbit
NOAEL: 5,040 mg/kg
Application Route: Skin contact
Exposure time: 45 Weeks
Aspiration Toxicity
Not classified based on available information.
Section 12. Ecological Information
Ecotoxicity
Components:
Tebuconazole:
- Toxicity to fish: LC50 (Oncorhynchus mykiss (rainbow trout)): 4.4 mg/l Exposure time: 96 h
- Toxicity to daphnia and other aquatic invertebrates: EC50 (Daphnia magna (Water flea)): 2.79 mg/l Exposure time: 48 h
- Toxicity to algae/aquatic plants: ErC50 (Lemna gibba (gibbous duckweed)): 0.237 mg/l Exposure time: 168 h
SAFETY DATA SHEET
DEDICATE FORTE STRESSGARD TURF FUNGICIDE
Version: 2.0 Revision Date: 06.11.2024 SDS Number: 11264709-00003 Date of last issue: 19.12.2023 Date of first issue: 27.10.2023
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- Toxicity to fish (Chronic toxicity): NOEC (Oncorhynchus mykiss (rainbow trout)): 0.012 mg/l Exposure time: 83 d
- Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity): NOEC (Daphnia magna (Water flea)): 0.01 mg/l Exposure time: 21 d
- Toxicity to microorganisms: EC50 (activated sludge): > 32 mg/l Exposure time: 0.5 h
Glycerine:
- Toxicity to fish: LC50 (Oncorhynchus mykiss (rainbow trout)): 54,000 mg/l Exposure time: 96 h
- Toxicity to daphnia and other aquatic invertebrates: EC50 (Daphnia magna (Water flea)): 1,955 mg/l Exposure time: 48 h
- Toxicity to microorganisms: NOEC (Pseudomonas putida): > 10,000 mg/l Exposure time: 16 h Method: DIN 38 412 Part 8
Alcohols, C16-18 and C18-unsatd., ethoxylated:
- Toxicity to fish: LC50 (Danio rerio (zebra fish)): > 1 - 10 mg/l Exposure time: 96 h Method: OECD Test Guideline 203
Alkylnaphthalenesulfonic acid, polymer with formaldehyde, sodium salt:
Toxicity to fish: LC50 (Danio rerio (zebra fish)): > 10 - 100 mg/l Exposure time: 96 h Method: OECD Test Guideline 203 Remarks: Based on data from similar materials
Toxicity to daphnia and other aquatic invertebrates: EC50 (Daphnia magna (Water flea)): > 100 mg/l Exposure time: 48 h Method: OECD Test Guideline 202 Remarks: Based on data from similar materials
Toxicity to algae/aquatic plants: EC50 (Pseudokirchneriella subcapitata (green algae)): > 100 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 Remarks: Based on data from similar materials
EC10 (Pseudokirchneriella subcapitata (green algae)): > 100 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 Remarks: Based on data from similar materials
SAFETY DATA SHEET
DEDICATE FORTE STRESSGARD TURF FUNGICIDE
Version: 2.0 Revision Date: 06.11.2024 SDS Number: 11264709-00003 Date of last issue: 19.12.2023 Date of first issue: 27.10.2023
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- Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity): EC10 (Daphnia magna (Water flea)): > 1 mg/l Exposure time: 21 d Method: OECD Test Guideline 211 Remarks: Based on data from similar materials
Reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H-isothiazol-3-one [EC no. 220-239-6] (3:1):
Toxicity to fish: LC50 (Oncorhynchus mykiss (rainbow trout)): 0.19 mg/l Exposure time: 96 h
Toxicity to daphnia and other aquatic invertebrates: EC50 (Daphnia magna (Water flea)): 0.16 mg/l Exposure time: 48 h
Toxicity to algae/aquatic plants: ErC50 (Skeletonema costatum (marine diatom)): 0.0052 mg/l Exposure time: 48 h
NOEC (Skeletonema costatum (marine diatom)): 0.00049 mg/l Exposure time: 48 h
Toxicity to fish (Chronic toxicity): NOEC (Pimephales promelas (fathead minnow)): 0.02 mg/l Exposure time: 36 d
Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity): NOEC (Daphnia magna (Water flea)): 0.10 mg/l Exposure time: 21 d
Persistence and Degradability
Components:
Glycerine:
- Biodegradability: Result: Readily biodegradable. Biodegradation: 92 % Exposure time: 30 d Method: OECD Test Guideline 301D
Alcohols, C16-18 and C18-unsatd., ethoxylated:
- Biodegradability: Result: Readily biodegradable. Method: OECD Test Guideline 301E
Alkylnaphthalenesulfonic acid, polymer with formaldehyde, sodium salt:
- Biodegradability: Result: Not readily biodegradable. Remarks: Based on data from similar materials
Reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H-isothiazol-3-one [EC no. 220-239-6] (3:1):
- Biodegradability: Result: Not readily biodegradable.
SAFETY DATA SHEET
DEDICATE FORTE STRESSGARD TURF FUNGICIDE
Version: 2.0 Revision Date: 06.11.2024 SDS Number: 11264709-00003 Date of last issue: 19.12.2023 Date of first issue: 27.10.2023
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Biodegradation: 62 % Exposure time: 28 d Method: OECD Test Guideline 301B
Bioaccumulative Potential
Components:
Tebuconazole:
- Bioaccumulation: Species: Lepomis macrochirus (Bluegill sunfish) Bioconcentration factor (BCF): 78
- Partition coefficient: n-octanol/water: log Pow: 3.7
Glycerine:
- Partition coefficient: n-octanol/water: log Pow: -1.75
Alcohols, C16-18 and C18-unsatd., ethoxylated:
- Partition coefficient: n-octanol/water: log Pow: > 4 Remarks: Calculation
Reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H-isothiazol-3-one [EC no. 220-239-6] (3:1):
- Partition coefficient: n-octanol/water: log Pow: < 1
Mobility in Soil
No data available
Other Adverse Effects
No data available
Section 13. Disposal Considerations
Disposal Methods
- Waste from residues: It is best to use all of the product in accordance with label directions. If it is necessary to dispose of unused product, please follow container label instructions and applicable local guidelines. Do not dispose of waste into sewer.
- Contaminated packaging: Follow advice on product label and/or leaflet. Empty containers retain residue and can be dangerous. Do not re-use empty containers.
SAFETY DATA SHEET
DEDICATE FORTE STRESSGARD TURF FUNGICIDE
Version: 2.0 Revision Date: 06.11.2024 SDS Number: 11264709-00003 Date of last issue: 19.12.2023 Date of first issue: 27.10.2023
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Section 14. Transport Information
International Regulations
UNRTDG
- UN number: UN 3082
- Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Tebuconazole, Reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H-isothiazol-3-one [EC no. 220-239-6] (3:1)
- Class: 9
- Packing group: III
- Labels: 9
- Environmentally hazardous: yes
IATA-DGR
- UN/ID No.: UN 3082
- Proper shipping name: Environmentally hazardous substance, liquid, n.o.s. (Tebuconazole, Reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H-isothiazol-3-one [EC no. 220-239-6] (3:1)
- Class: 9
- Packing group: III
- Labels: Miscellaneous
- Packing instruction (cargo aircraft): 964
- Packing instruction (passenger aircraft): 964
- Environmentally hazardous: yes
IMDG-Code
- UN number: UN 3082
- Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Tebuconazole, Reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H-isothiazol-3-one [EC no. 220-239-6] (3:1)
- Class: 9
- Packing group: III
- Labels: 9
- EmS Code: F-A, S-F
- Marine pollutant: yes
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied.
National Regulations
ADG
- UN number: UN 3082
- Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
SAFETY DATA SHEET
DEDICATE FORTE STRESSGARD TURF FUNGICIDE
Version: 2.0 Revision Date: 06.11.2024 SDS Number: 11264709-00003 Date of last issue: 19.12.2023 Date of first issue: 27.10.2023
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N.O.S. (Tebuconazole, Reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H-isothiazol-3-one [EC no. 220-239-6] (3:1)
- Class: 9
- Packing group: III
- Labels: 9
- Hazchem Code: •3Z
- Environmentally hazardous: yes
Special Precautions for User
The transport classification(s) provided herein are for informational purposes only, and solely based upon the properties of the unpackaged material as it is described within this Safety Data Sheet. Transportation classifications may vary by mode of transportation, package sizes, and variations in regional or country regulations.
Section 15. Regulatory Information
Safety, Health and Environmental Regulations/legislation Specific for the Substance or Mixture
- Therapeutic Goods (Poisons Standard) Instrument: Schedule 5 (Please use the original publication to check for specific uses, specific conditions or threshold limits that might apply for this chemical)
- Prohibition/Licensing Requirements: There is no applicable prohibition, authorisation and restricted use requirements, including for carcinogens referred to in Schedule 10 of the model WHS Act and Regulations.
- Active substance: 240 g/l Tebuconazole
Section 16: Any Other Relevant Information
Further Information
- Revision Date: 06.11.2024
- Sources of key data used to compile the Safety Data Sheet: Internal technical data, data from raw material SDSs, OECD eChem Portal search results and European Chemicals Agency,
- Items where changes have been made to the previous version are highlighted in the body of this document by two vertical lines.
- Date format: dd.mm.yyyy
Full Text of Other Abbreviations
- AU OEL: Australia. Workplace Exposure Standards for Airborne Con-
SAFETY DATA SHEET
DEDICATE FORTE STRESSGARD TURF FUNGICIDE
Version: 2.0 Revision Date: 06.11.2024 SDS Number: 11264709-00003 Date of last issue: 19.12.2023 Date of first issue: 27.10.2023
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taminants.
- AU OEL / TWA: Exposure standard - time weighted average
AIIC - Australian Inventory of Industrial Chemicals; ANTT - National Agency for Transport by Land of Brazil; ASTM - American Society for the Testing of Materials; bw - Body weight; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the German Institute for Standardisation; DSL - Domestic Substances List (Canada); ECx - Concentration associated with x% response; ELx - Loading rate associated with x% response; EmS - Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized System; GLP - Good Laboratory Practice; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; IBC - International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO - International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50 - Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - International Convention for the Prevention of Pollution from Ships; n.o.s. - Not Otherwise Specified; Nch - Chilean Norm; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NOM - Official Mexican Norm; NTP - National Toxicology Program; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure Activity Relationship; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals; SADT - Self-Accelerating Decomposition Temperature; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TDG - Transportation of Dangerous Goods; TECI - Thailand Existing Chemicals Inventory; TSCA - Toxic Substances Control Act (United States); UN - United Nations; UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods; vPvB - Very Persistent and Very Bioaccumulative; WHMIS - Workplace Hazardous Materials Information System
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and shall not be considered a warranty or quality specification of any type. The information provided relates only to the specific material identified at the top of this SDS and may not be valid when the SDS material is used in combination with any other materials or in any process, unless specified in the text. Material users should review the information and recommendations in the specific context of their intended manner of handling, use, processing and storage, including an assessment of the appropriateness of the SDS material in the user’s end product, if applicable.
AU / EN