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SAFETY DATA SHEET

TETRINO TURF INSECTICIDE

Version	Revision Date:	SDS Number:	Date of last issue: 13.09.2023
1.1	29.03.2024	11264708-00002	Date of first issue: 13.09.2023

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Section 1: Identification

Product name : TETRINO TURF INSECTICIDE

Product code : Article/SKU: 87354520 UVP: 84500089 Specification: 102000032078

Manufacturer or Supplier's Details

Company	:	2022 Environmental Science AU Pty Ltd
Address	:	Suite 2.06, Level 2, 737 Burwood Road Hawthorn East, Australia 3123
Emergency telephone number	:

Recommended Use of the Chemical and Restrictions on Use

Recommended use	:	Insecticide
Restrictions on use	:	See product label for restrictions.

Section 2. Hazards Identification

Ghs Classification

Not a hazardous substance or mixture.

Ghs Label Elements

No hazard pictogram, no signal word, no hazard statement(s), no precautionary statement(s) required

Other Hazards Which Do Not Result in Classification

None known.

Section 3. Composition/information on Ingredients

Substance / Mixture : Mixture

Chemical nature : Suspension concentrate (=flowable concentrate)(SC)

Components

Chemical name	CAS-No.	Concentration (% w/w)
Glycerine	56-81-5	>= 10 -< 30
Tetraniliprole	1229654-66-3	>= 1 -< 10
Propylene glycol	57-55-6	< 10
2-Propanol, reaction products with naphtha-	-6	>= 1 -< 3

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lene, sulfonated, sodium salts

Section 4. First Aid Measures

If inhaled	:	If inhaled, remove to fresh air. Get medical attention if symptoms occur.
In case of skin contact	:	Wash with water and soap as a precaution. Get medical attention if symptoms occur.
In case of eye contact	:	Flush eyes with water as a precaution. Get medical attention if irritation develops and persists.
If swallowed	:	If swallowed, DO NOT induce vomiting. Get medical attention if symptoms occur. Rinse mouth thoroughly with water.
Most important symptoms and effects, both acute and delayed	:	No symptoms known or expected.
Protection of first-aiders	:	No special precautions are necessary for first aid responders.
Notes to physician	:	Appropriate supportive and symptomatic treatment as indicated by the patient's condition is recommended.

Section 5. Firefighting Measures

Suitable extinguishing media	:	Water spray Alcohol-resistant foam Carbon dioxide (CO2) Dry chemical
Unsuitable extinguishing media	:	High volume water jet
Specific hazards during firefighting	:	Vapours may form explosive mixtures with air. Exposure to combustion products may be a hazard to health.
Hazardous combustion products	:	Chlorine compounds Fluorine compounds Carbon oxides Nitrogen oxides (NOx) Sulphur oxides Metal oxides
Specific extinguishing methods	:	Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Use water spray to cool unopened containers. Remove undamaged containers from fire area if it is safe to do so. Evacuate area.

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Special protective equipment for firefighters	:	Wear self-contained breathing apparatus for firefighting if necessary. Use personal protective equipment.
Hazchem Code	:	•3Z

Section 6. Accidental Release Measures

Personal precautions, protective equipment and emergency procedures	:	Follow safe handling advice (see section 7) and personal protective equipment recommendations (see section 8).
Environmental precautions	:	Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Prevent spreading over a wide area (e.g. by containment or oil barriers). Retain and dispose of contaminated wash water. Local authorities should be advised if significant spillages cannot be contained.
Methods and materials for containment and cleaning up	:	Soak up with inert absorbent material. For large spills, provide dyking or other appropriate containment to keep material from spreading. If dyked material can be pumped, store recovered material in appropriate container. Clean up remaining materials from spill with suitable absorbent. Local or national regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which regulations are applicable. Sections 13 and 15 of this SDS provide information regarding certain local or national requirements.

Section 7. Handling and Storage

Technical measures	:	See Engineering measures under EXPOSURE CONTROLS/PERSONAL PROTECTION section.
Local/Total ventilation	:	Use only with adequate ventilation.
Advice on safe handling	:	Avoid prolonged or repeated contact with skin. Handle in accordance with good industrial hygiene and safety practice, based on the results of the workplace exposure assessment Take care to prevent spills, waste and minimize release to the environment.
Hygiene measures	:	If exposure to chemical is likely during typical use, provide eye flushing systems and safety showers close to the working place.

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When using do not eat, drink or smoke. Wash contaminated clothing before re-use.

Conditions for safe storage	:	Keep in properly labelled containers. Store in accordance with the particular national regulations.
Materials to avoid	:	Do not store with the following product types: Strong oxidizing agents

Section 8. Exposure Controls/personal Protection

Components with Workplace Control Parameters

Components	CAS-No.	Value type (Form of exposure)	Control parameters / Permissible concentration	Basis
Glycerine	56-81-5	TWA (Mist)	10 mg/m3	AU OEL
Propylene glycol	57-55-6	TWA (particulate)	10 mg/m3	AU OEL
		TWA (Total (vapour and particles))	150 ppm 474 mg/m3	AU OEL

Engineering measures	:	Ensure adequate ventilation, especially in confined areas. Minimize workplace exposure concentrations.

Personal Protective Equipment

Respiratory protection	:	If adequate local exhaust ventilation is not available or exposure assessment demonstrates exposures outside the recommended guidelines, use respiratory protection.
Filter type	:	Combined particulates and organic vapour type
Hand protection
Material	:	Nitrile rubber
Break through time	:	480 min
Glove thickness	:	0.4 mm
Protective index	:	Class 6
Remarks	:	Choose gloves to protect hands against chemicals depending on the concentration and quantity of the hazardous substance and specific to place of work. For special applications, we recommend clarifying the resistance to chemicals of the aforementioned protective gloves with the glove manufacturer. Wash hands before breaks and at the end of workday.
Eye protection	:	Wear the following personal protective equipment: Safety glasses

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Skin and body protection : Skin should be washed after contact.

Section 9. Physical and Chemical Properties

Appearance	:	suspension
Colour	:	white, beige
Odour	:	slight, like soap
Odour Threshold	:	No data available
pH	:	4 - 5 (23 °C) Concentration: 100 %
Melting point/freezing point	:	No data available
Initial boiling point and boiling range	:	No data available
Flash point	:	> 94 °C Method: ASTM D 93, closed cup
Evaporation rate	:	No data available
Flammability (solid, gas)	:	Not applicable
Flammability (liquids)	:	No data available
Upper explosion limit / Upper flammability limit	:	No data available
Lower explosion limit / Lower flammability limit	:	No data available
Vapour pressure	:	No data available
Relative vapour density	:	No data available
Density	:	ca. 1.05 g/cm³ (20 °C)
Solubility(ies) Water solubility	:	dispersible
Partition coefficient: n-octanol/water	:	Not applicable

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Auto-ignition temperature	:	No data available
Decomposition temperature	:	No data available
Viscosity Viscosity, dynamic	:	352 - 950 mPa.s ( 20 °C)
Viscosity, kinematic	:	No data available
Flow time	:	45 - 55 s (20 °C)
Explosive properties	:	Not explosive
Oxidizing properties	:	The substance or mixture is not classified as oxidizing.
Minimum ignition energy	:	Not applicable
Particle characteristics Particle size	:	<= 10 µm

Section 10. Stability and Reactivity

Reactivity	:	Not classified as a reactivity hazard.
Chemical stability	:	Stable under normal conditions.
Possibility of hazardous reactions	:	Vapours may form explosive mixture with air. Can react with strong oxidizing agents.
Conditions to avoid	:	None known.
Incompatible materials	:	Oxidizing agents
Hazardous decomposition products	:	No hazardous decomposition products are known.

Section 11. Toxicological Information

Exposure routes	:	Inhalation Skin contact Ingestion Eye contact

Acute Toxicity

Not classified based on available information.

Product:

| Acute oral toxicity | : | Acute toxicity estimate: > 2,000 mg/kg |

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Method: Calculation method

Acute inhalation toxicity	:	Acute toxicity estimate: > 5 mg/l Exposure time: 4 h Test atmosphere: dust/mist Method: Calculation method

Components:

Glycerine:

Acute oral toxicity	:	LD50 (Rat): > 5,000 mg/kg
Acute dermal toxicity	:	LD50 (Guinea pig): > 5,000 mg/kg

Tetraniliprole:

Acute oral toxicity	:	LD50 (Rat): > 2,000 mg/kg Method: OECD Test Guideline 423 Assessment: The substance or mixture has no acute oral toxicity
Acute inhalation toxicity	:	LC50 (Rat): > 5.01 mg/l Exposure time: 4 h Test atmosphere: dust/mist Method: OECD Test Guideline 403
Acute dermal toxicity	:	LD50 (Rat): > 2,000 mg/kg Method: OECD Test Guideline 402 Assessment: The substance or mixture has no acute dermal toxicity

Propylene Glycol:

Acute oral toxicity	:	LD50 (Rat): 22,000 mg/kg
Acute inhalation toxicity	:	LC50 (Rat): > 44.9 mg/l Exposure time: 4 h Test atmosphere: dust/mist
Acute dermal toxicity	:	LD50 (Rabbit): > 2,000 mg/kg Assessment: The substance or mixture has no acute dermal toxicity

2-Propanol, Reaction Products with Naphthalene, Sulfonated, Sodium Salts:

Acute oral toxicity	:	LD50 (Rat): > 453 - 1,368 mg/kg Method: OECD Test Guideline 401
Acute inhalation toxicity	:	LC50 (Rat, male): 1.09 mg/l Exposure time: 4 h Test atmosphere: dust/mist Method: OECD Test Guideline 403

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Acute dermal toxicity	:	LD50 (Rabbit, male): > 2,000 mg/kg Remarks: Based on data from similar materials

Skin Corrosion/irritation

Not classified based on available information.

Components:

Glycerine:

Species	:	Rabbit
Result	:	No skin irritation

Tetraniliprole:

Species	:	Rabbit
Method	:	OECD Test Guideline 404
Result	:	No skin irritation

Propylene Glycol:

Species	:	Rabbit
Method	:	OECD Test Guideline 404
Result	:	No skin irritation

2-Propanol, Reaction Products with Naphthalene, Sulfonated, Sodium Salts:

Species	:	Rabbit
Result	:	No skin irritation

Serious Eye Damage/eye Irritation

Not classified based on available information.

Product:

Species	:	Rabbit
Result	:	No eye irritation

Components:

Glycerine:

Species	:	Rabbit
Result	:	No eye irritation

Tetraniliprole:

Species	:	Rabbit
Result	:	No eye irritation
Method	:	OECD Test Guideline 405

Propylene Glycol:

Species	:	Rabbit
Result	:	No eye irritation

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Method	:	OECD Test Guideline 405

2-Propanol, Reaction Products with Naphthalene, Sulfonated, Sodium Salts:

Species	:	Rabbit
Result	:	Irreversible effects on the eye

Respiratory or Skin Sensitisation

Skin Sensitisation

Not classified based on available information.

Respiratory Sensitisation

Not classified based on available information.

Product:

Test Type	:	Local lymph node assay (LLNA)
Species	:	Mouse
Result	:	Does not cause skin sensitisation.

Components:

Tetraniliprole:

Test Type	:	Local lymph node assay (LLNA)
Exposure routes	:	Skin contact
Species	:	Mouse
Method	:	OECD Test Guideline 429
Result	:	positive
Assessment	:	Probability or evidence of low to moderate skin sensitisation rate in humans

Propylene Glycol:

Test Type	:	Maximisation Test
Exposure routes	:	Skin contact
Species	:	Guinea pig
Result	:	negative

Chronic Toxicity

Germ Cell Mutagenicity

Not classified based on available information.

Components:

Glycerine:

Genotoxicity in vitro	:	Test Type: In vitro mammalian cell gene mutation test Result: negative Test Type: Bacterial reverse mutation assay (AMES) Result: negative

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	Test Type: Chromosome aberration test in vitro Result: negative Test Type: DNA damage and repair, unscheduled DNA synthesis in mammalian cells (in vitro) Result: negative

Tetraniliprole:

Genotoxicity in vitro	:	Test Type: Bacterial reverse mutation assay (AMES) Method: OECD Test Guideline 471 Result: negative Test Type: In vitro mammalian cell gene mutation test Method: OECD Test Guideline 476 Result: negative Test Type: Chromosome aberration test in vitro Method: OECD Test Guideline 473 Result: negative
Genotoxicity in vivo	:	Test Type: Mammalian erythrocyte micronucleus test (in vivo cytogenetic assay) Species: Mouse Application Route: Ingestion Method: OECD Test Guideline 474 Result: negative

Propylene Glycol:

Genotoxicity in vitro	:	Test Type: Bacterial reverse mutation assay (AMES) Result: negative Test Type: Chromosome aberration test in vitro Method: OECD Test Guideline 473 Result: negative
Genotoxicity in vivo	:	Test Type: Mammalian erythrocyte micronucleus test (in vivo cytogenetic assay) Species: Mouse Application Route: Intraperitoneal injection Result: negative

2-Propanol, Reaction Products with Naphthalene, Sulfonated, Sodium Salts:

| Genotoxicity in vitro | : | Test Type: Bacterial reverse mutation assay (AMES)
Method: OECD Test Guideline 471
Result: negative

Test Type: In vitro mammalian cell gene mutation test
Method: OECD Test Guideline 476
Result: negative |

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	Test Type: Chromosome aberration test in vitro Method: OECD Test Guideline 473 Result: negative

Carcinogenicity

Not classified based on available information.

Components:

Glycerine:

Species	:	Rat
Application Route	:	Ingestion
Exposure time	:	2 Years
Result	:	negative

Tetraniliprole:

Species	:	Rat
Application Route	:	Ingestion
Exposure time	:	104 weeks
Method	:	OECD Test Guideline 453
Result	:	negative

Propylene Glycol:

Species	:	Rat
Application Route	:	Ingestion
Exposure time	:	2 Years
Result	:	negative

Reproductive Toxicity

Not classified based on available information.

Components:

Glycerine:

Effects on fertility	:	Test Type: Two-generation reproduction toxicity study Species: Rat Application Route: Ingestion Result: negative
Effects on foetal development	:	Test Type: Embryo-foetal development Species: Rat Application Route: Ingestion Result: negative

Tetraniliprole:

| Effects on fertility | : | Test Type: Two-generation reproduction toxicity study
Species: Rat
Application Route: Ingestion |

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	Method: OECD Test Guideline 416 Result: negative
Effects on foetal development	:

Propylene Glycol:

Effects on fertility	:	Test Type: Two-generation reproduction toxicity study Species: Mouse Application Route: Ingestion Result: negative
Effects on foetal development	:	Test Type: Embryo-foetal development Species: Mouse Application Route: Ingestion Result: negative

2-Propanol, Reaction Products with Naphthalene, Sulfonated, Sodium Salts:

Effects on fertility	:	Test Type: Combined repeated dose toxicity study with the reproduction/developmental toxicity screening test Species: Rat Application Route: Ingestion Method: OECD Test Guideline 422 Result: negative
Effects on foetal development	:	Test Type: Combined repeated dose toxicity study with the reproduction/developmental toxicity screening test Species: Rat Application Route: Ingestion Method: OECD Test Guideline 422 Result: negative

Stot - Single Exposure

Not classified based on available information.

Components:

2-Propanol, Reaction Products with Naphthalene, Sulfonated, Sodium Salts:

Assessment	:	May cause respiratory irritation.

Stot - Repeated Exposure

Not classified based on available information.

Components:

2-Propanol, Reaction Products with Naphthalene, Sulfonated, Sodium Salts:

| Assessment | : | No significant health effects observed in animals at concentra- |

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tions of 0.2 mg/l/6h/d or less.

Repeated Dose Toxicity

Components:

Glycerine:

Species	:	Rat
NOAEL	:	0.167 mg/l
LOAEL	:	0.622 mg/l
Application Route	:	inhalation (dust/mist/fume)
Exposure time	:	13 Weeks
Species	:	Rat
NOAEL	:	8,000 - 10,000 mg/kg
Application Route	:	Ingestion
Exposure time	:	2 yr
Species	:	Rabbit
NOAEL	:	5,040 mg/kg
Application Route	:	Skin contact
Exposure time	:	45 Weeks

Tetraniliprole:

Species	:	Rat, male
NOAEL	:	159 mg/kg
LOAEL	:	741 mg/kg
Application Route	:	Ingestion
Exposure time	:	24 Months
Method	:	OECD Test Guideline 453
Species	:	Rat
NOAEL	:	>= 1,000 mg/kg
Application Route	:	Skin contact
Exposure time	:	28 Days
Method	:	OECD Test Guideline 410

Propylene Glycol:

Species	:	Rat, male
NOAEL	:	>= 1,700 mg/kg
Application Route	:	Ingestion
Exposure time	:	2 yr

2-Propanol, Reaction Products with Naphthalene, Sulfonated, Sodium Salts:

Species	:	Rat
NOAEL	:	100 mg/kg
LOAEL	:	300 mg/kg
Application Route	:	Ingestion
Exposure time	:	36 - 52 Days
Method	:	OECD Test Guideline 422

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Species	:	Rat
NOAEL	:	0.004 mg/l
LOAEL	:	0.01 mg/l
Application Route	:	inhalation (dust/mist/fume)
Exposure time	:	90 Days
Method	:	OECD Test Guideline 413

Aspiration Toxicity

Not classified based on available information.

Section 12. Ecological Information

Ecotoxicity

Components:

Glycerine:

Toxicity to fish	:	LC50 (Oncorhynchus mykiss (rainbow trout)): 54,000 mg/l Exposure time: 96 h
Toxicity to daphnia and other aquatic invertebrates	:	EC50 (Daphnia magna (Water flea)): 1,955 mg/l Exposure time: 48 h
Toxicity to microorganisms	:	NOEC (Pseudomonas putida): > 10,000 mg/l Exposure time: 16 h Method: DIN 38 412 Part 8

Tetraniliprole:

Toxicity to fish	:	LC50 (Oncorhynchus mykiss (rainbow trout)): > 10 mg/l Exposure time: 96 h Method: OECD Test Guideline 203 Remarks: No toxicity at the limit of solubility
Toxicity to daphnia and other aquatic invertebrates	:	EC50 (Daphnia magna (Water flea)): 0.1733 mg/l Exposure time: 48 h Method: OECD Test Guideline 202
Toxicity to algae/aquatic plants	:	ErC50 (Skeletonema costatum (marine diatom)): 1.49 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 NOEC (Skeletonema costatum (marine diatom)): 0.429 mg/l Exposure time: 72 h Method: OECD Test Guideline 201
Toxicity to fish (Chronic toxicity)	:	NOEC (Pimephales promelas (fathead minnow)): 2.50 mg/l Exposure time: 33 d Method: OECD Test Guideline 210
Toxicity to daphnia and other	:	EC10 (Chironomus riparius (harlequin fly)): 0.00071 mg/l

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aquatic invertebrates (Chronic toxicity)	Exposure time: 28 d
Toxicity to microorganisms	NOEC (activated sludge): >= 100 mg/l Exposure time: 3 h Method: OECD Test Guideline 209

Propylene Glycol:

Toxicity to fish	:	LC50 (Oncorhynchus mykiss (rainbow trout)): 40,613 mg/l Exposure time: 96 h
Toxicity to daphnia and other aquatic invertebrates	:	EC50 (Ceriodaphnia dubia (water flea)): 18,340 mg/l Exposure time: 48 h
Toxicity to algae/aquatic plants	:	ErC50 (Skeletonema costatum (marine diatom)): 19,300 mg/l Exposure time: 72 h Method: OECD Test Guideline 201
Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity)	:	NOEC (Ceriodaphnia dubia (water flea)): 13,020 mg/l Exposure time: 7 d
Toxicity to microorganisms	:	NOEC (Pseudomonas putida): > 20,000 mg/l Exposure time: 18 h

2-Propanol, Reaction Products with Naphthalene, Sulfonated, Sodium Salts:

Toxicity to fish	:	LC50 (Oncorhynchus mykiss (rainbow trout)): > 100 mg/l Exposure time: 96 h Method: OECD Test Guideline 203
Toxicity to daphnia and other aquatic invertebrates	:	EC50 (Daphnia magna (Water flea)): > 100 mg/l Exposure time: 48 h Method: OECD Test Guideline 202
Toxicity to algae/aquatic plants	:	ErC50 (Raphidocelis subcapitata (freshwater green alga)): > 200 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 NOEC (Raphidocelis subcapitata (freshwater green alga)): 12.5 mg/l Exposure time: 72 h Method: OECD Test Guideline 201
Toxicity to microorganisms	:	NOEC (activated sludge): 0.16 mg/l Exposure time: 3 h Method: OECD Test Guideline 209

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Persistence and Degradability

Components:

Glycerine:

Biodegradability	:	Result: Readily biodegradable. Biodegradation: 92 % Exposure time: 30 d Method: OECD Test Guideline 301D

Tetraniliprole:

Biodegradability	:	Result: Not readily biodegradable. Biodegradation: 1 % Exposure time: 28 d Method: OECD Test Guideline 301F

Propylene Glycol:

Biodegradability	:	Result: Readily biodegradable. Biodegradation: 98.3 % Exposure time: 28 d Method: OECD Test Guideline 301F

2-Propanol, Reaction Products with Naphthalene, Sulfonated, Sodium Salts:

Biodegradability	:	Result: Not readily biodegradable. Biodegradation: 0 % Exposure time: 29 d Method: OECD Test Guideline 301B

Bioaccumulative Potential

Components:

Glycerine:

Partition coefficient: n-octanol/water	:	log Pow: -1.75

Tetraniliprole:

Bioaccumulation	:	Species: Lepomis macrochirus (Bluegill sunfish) Bioconcentration factor (BCF): 7.3 Method: OECD Test Guideline 305
Partition coefficient: n-octanol/water	:	log Pow: 2.6 Method: OECD Test Guideline 117

Propylene Glycol:

Partition coefficient: n-octanol/water	:	log Pow: -1.07 Method: Regulation (EC) No. 440/2008, Annex, A.8

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2-Propanol, Reaction Products with Naphthalene, Sulfonated, Sodium Salts:

Partition coefficient: n-octanol/water	:	log Pow: -0.27

Mobility in Soil

No data available

Other Adverse Effects

No data available

Section 13. Disposal Considerations

Disposal Methods

Waste from residues	:	It is best to use all of the product in accordance with label directions. If it is necessary to dispose of unused product, please follow container label instructions and applicable local guidelines. Do not dispose of waste into sewer.
Contaminated packaging	:	Follow advice on product label and/or leaflet. Empty containers retain residue and can be dangerous. Do not re-use empty containers.

Section 14. Transport Information

International Regulations

Unrtdg

UN number	:	UN 3082
Proper shipping name	:	ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Tetraniliprole, Reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H-isothiazol-3-one [EC no. 220-239-6] (3:1)
Class	:	9
Packing group	:	III
Labels	:	9
Environmentally hazardous	:	yes

Iata-dgr

UN/ID No.	:	UN 3082
Proper shipping name	:	Environmentally hazardous substance, liquid, n.o.s. (Tetraniliprole, Reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H-isothiazol-3-one [EC no. 220-239-6] (3:1)
Class	:	9
Packing group	:	III
Labels	:	Miscellaneous
Packing instruction (cargo aircraft)	:	964

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Packing instruction (passenger aircraft)	:	964
Environmentally hazardous	:	yes

Imdg-code

UN number	:	UN 3082
Proper shipping name	:	ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Tetraniliprole, Reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H-isothiazol-3-one [EC no. 220-239-6] (3:1)
Class	:	9
Packing group	:	III
Labels	:	9
EmS Code	:	F-A, S-F
Marine pollutant	:	yes

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied.

National Regulations

Adg

UN number	:	UN 3082
Proper shipping name	:	ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Tetraniliprole, Reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H-isothiazol-3-one [EC no. 220-239-6] (3:1)
Class	:	9
Packing group	:	III
Labels	:	9
Hazchem Code	:	•3Z
Environmentally hazardous	:	yes

Special Precautions for User

The transport classification(s) provided herein are for informational purposes only, and solely based upon the properties of the unpackaged material as it is described within this Safety Data Sheet. Transportation classifications may vary by mode of transportation, package sizes, and variations in regional or country regulations.

Section 15. Regulatory Information

Safety, health and environmental regulations/legislation specific for the substance or mixture
Therapeutic Goods (Poisons Standard) Instrument	:	Schedule 5 (Please use the original publication to check for specific uses, specific conditions or threshold limits that might apply for this chemical)
Prohibition/Licensing Requirements	:	There is no applicable prohibition, authorisation and restricted use requirements, including for carcinogens referred to in Schedule 10 of

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the model WHS Act and Regulations.

Product Type	:	Insecticides, acaricides and products to control other arthropods
Active substance	:	43 g/l Tetraniliprole

Section 16: Any Other Relevant Information

Further Information

Revision Date	:	29.03.2024
Sources of key data used to compile the Safety Data Sheet	:	Internal technical data, data from raw material SDSs, OECD eChem Portal search results and European Chemicals Agency,
Date format	:	dd.mm.yyyy

Full Text of Other Abbreviations

AU OEL : Australia. Workplace Exposure Standards for Airborne Contaminants.

AU OEL / TWA : Exposure standard - time weighted average

AIIC - Australian Inventory of Industrial Chemicals; ANTT - National Agency for Transport by Land of Brazil; ASTM - American Society for the Testing of Materials; bw - Body weight; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the German Institute for Standardisation; DSL - Domestic Substances List (Canada); ECx - Concentration associated with x% response; ELx - Loading rate associated with x% response; EmS - Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized System; GLP - Good Laboratory Practice; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; IBC - International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO - International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50 - Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - International Convention for the Prevention of Pollution from Ships; n.o.s. - Not Otherwise Specified; Nch - Chilean Norm; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NOM - Official Mexican Norm; NTP - National Toxicology Program; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure Activity Relationship; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals; SADT - Self-Accelerating Decomposition Temperature; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TDG - Trans-

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portation of Dangerous Goods; TECI - Thailand Existing Chemicals Inventory; TSCA - Toxic Substances Control Act (United States); UN - United Nations; UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods; vPvB - Very Persistent and Very Bioaccumulative; WHMIS - Workplace Hazardous Materials Information System

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and shall not be considered a warranty or quality specification of any type. The information provided relates only to the specific material identified at the top of this SDS and may not be valid when the SDS material is used in combination with any other materials or in any process, unless specified in the text. Material users should review the information and recommendations in the specific context of their intended manner of handling, use, processing and storage, including an assessment of the appropriateness of the SDS material in the user's end product, if applicable.

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