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Safety Data Sheet

SDS - BASF Lexicon Fungicide - 241113

English 577 KB PDF Valid until 2029-11-13

Applies to Lexicon Intrinsic | Fungicide

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Safety data sheet

Page: 1/22 BASF safety data sheet. This document has been drafted following generic rules for safety data sheets. It does not replace the safety data sheet provided according to Regulation (EC) No 1907/2006. Date / Revised: 13.09.2024 Version: 6.0 Date / Previous version: 29.07.2022 Previous version: 5.1 Product: Lexicon® Intrinsic Brand Fungicide (ID no. 30604404/SDS_CPA_EU/EN) Date of print 13.11.2024

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier Lexicon® Intrinsic Brand Fungicide

1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses: crop protection product, fungicide

E-mail address:

1.4. Emergency telephone number International emergency number:

Page: 2/22 BASF safety data sheet. This document has been drafted following generic rules for safety data sheets. It does not replace the safety data sheet provided according to Regulation (EC) No 1907/2006. Date / Revised: 13.09.2024 Version: 6.0 Date / Previous version: 29.07.2022 Previous version: 5.1 Product: Lexicon® Intrinsic Brand Fungicide (ID no. 30604404/SDS_CPA_EU/EN) Date of print 13.11.2024

SECTION 2: Hazards Identification

2.1. Classification of the substance or mixture For the classification of the mixture the following methods have been applied: extrapolation on the concentration levels of the hazardous substances, on basis of test results and after evaluation of experts. The methodologies used are mentioned at the respective test results.

According to Regulation (EC) No 1272/2008 [CLP] Acute Tox. 4 (oral) H302 Harmful if swallowed. Skin Sens. 1 H317 May cause an allergic skin reaction. Repr. Additional category for effects on or via lactation. H362 May cause harm to breast-fed children. Repr. 2 H361d Suspected of damaging the unborn child. STOT SE 3 H335 May cause respiratory irritation. STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure. Aquatic Acute 1 H400 Very toxic to aquatic life. Aquatic Chronic 1 H410 Very toxic to aquatic life with long lasting effects.

For the classifications not written out in full in this section the full text can be found in section 16.

2.2. Label elements According to Regulation (EC) No 1272/2008 [CLP] Globally Harmonized System, EU (GHS) Pictogram: [Exclamation mark, Health hazard, Environment]

Signal Word: Warning

Hazard Statement: H302 Harmful if swallowed. H317 May cause an allergic skin reaction. H373 May cause damage to organs through prolonged or repeated exposure. H362 May cause harm to breast-fed children. H335 May cause respiratory irritation. H361d Suspected of damaging the unborn child. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. EUH401 To avoid risks to human health and the environment, comply with the instructions for use.

Precautionary Statement: P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children. P103 Read carefully and follow all instructions.

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Precautionary Statements (Prevention): P280 Wear protective gloves, protective clothing and eye protection or face protection. P271 Use only outdoors or in a well-ventilated area. P260 Do not breathe dust/gas/mist/vapours. P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P272 Contaminated work clothing should not be allowed out of the workplace. P270 Do not eat, drink or smoke when using this product. P264 Wash contaminated body parts thoroughly after handling. P263 Avoid contact during pregnancy and while nursing.

Precautionary Statements (Response): P312 Call a POISON CENTER or physician if you feel unwell. P308 + P313 IF exposed or concerned: Get medical attention. P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P333 + P313 If skin irritation or rash occurs: Get medical attention. P330 Rinse mouth. P391 Collect spillage. P362 + P364 Take off contaminated clothing and wash it before reuse.

Precautionary Statements (Storage): P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up.

Precautionary Statements (Disposal): P501 Dispose of contents and container to hazardous or special waste collection point.

Labeling of special preparations (GHS): May produce an allergic reaction. Contains: 1,2-benzisothiazol-3(2H)-one

Hazard determining component(s) for labelling: pyraclostrobin (ISO); methyl N-{2-[1-(4- chlorophenyl)-1H-pyrazol-3-yloxymethyl]phenyl}(N-methoxy)carbamate, Fluxapyroxad, 2-Methyl-2H-isothiazol-3-one

2.3. Other hazards According to Regulation (EC) No 1272/2008 [CLP] See section 12 - Results of PBT and vPvB assessment. If applicable information is provided in this section on other hazards which do not result in classification but which may contribute to the overall hazards of the substance or mixture. Product does not contain a substance above legal limits included in the list established in accordance with Article 59(1) of Regulation (EC) No 1907/2006 for having endocrine disrupting properties or is identified to have endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605.

Page: 4/22 BASF safety data sheet. This document has been drafted following generic rules for safety data sheets. It does not replace the safety data sheet provided according to Regulation (EC) No 1907/2006. Date / Revised: 13.09.2024 Version: 6.0 Date / Previous version: 29.07.2022 Previous version: 5.1 Product: Lexicon® Intrinsic Brand Fungicide (ID no. 30604404/SDS_CPA_EU/EN) Date of print 13.11.2024

SECTION 3: Composition/Information on Ingredients

3.1. Substances Not applicable

3.2. Mixtures Chemical nature crop protection product, fungicide, suspension concentrate (SC)

Regulatory relevant ingredients pyraclostrobin (ISO); methyl N-{2-[1-(4-chlorophenyl)-1H-pyrazol-3-yloxymethyl]phenyl}(N-methoxy)carbamate Content (W/W): 28.58 % CAS Number: 175013-18-0 INDEX-Number: 613-272-00-6 Substance with EU occupational exposure limit Acute Tox. 3 (Inhalation - mist) Acute Tox. 4 (oral) Skin Irrit. 2 Repr. 2 (unborn child) STOT SE 3 (irr. to respiratory syst.) STOT RE (Liver, Nasal cavity, Gastrointestinal tract) 2 Aquatic Acute 1 Aquatic Chronic 1 M-factor acute: 100 M-factor chronic: 100 H315, H331, H302, H335, H361d, H373, H400, H410 Acute toxicity estimate: oral: 450 mg/kg Inhalation: 0.58 mg/l

Fluxapyroxad Content (W/W): 14.33 % CAS Number: 907204-31-3 Substance with EU occupational exposure limit Repr. Add. cat. lact. Aquatic Acute 1 Aquatic Chronic 1 M-factor acute: 1 M-factor chronic: 1 H362, H400, H410

Residues (petroleum), catalytic reformer fractionator, sulfonated,polymers with formaldehyde, sodium salts Content (W/W): < 5 % CAS Number: 68425-94-5 Eye Dam./Irrit. 2 Aquatic Chronic 3 H319, H412

Benzenesulfonic acid, hydroxy-, polymer with formaldehyde, phenol and urea, sodium salt

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Content (W/W): < 5 % CAS Number: 102980-04-1 Eye Dam./Irrit. 2 Aquatic Chronic 3 H319, H412

bronopol (INN) Content (W/W): < 0.05 % CAS Number: 52-51-7 EC-Number: 200-143-0 REACH registration number: 01- 2119980938-15 INDEX-Number: 603-085-00-8 Acute Tox. 3 (Inhalation - dust) Acute Tox. 3 (oral) Acute Tox. 4 (dermal) Skin Irrit. 2 Eye Dam. 1 STOT SE 3 (irr. to respiratory syst.) Aquatic Acute 1 Aquatic Chronic 1 M-factor acute: 10 M-factor chronic: 10 H318, H315, H312, H335, H301 + H331, H400, H410 Differing classification according to current knowledge and the criteria given in Annex I of Regulation (EC) No. 1272/2008 Aquatic Chronic 1 Aquatic Acute 1 M-factor acute: 100 M-factor chronic: 10

1,2-benzisothiazol-3(2H)-one Content (W/W): < 0.01 % CAS Number: 2634-33-5 EC-Number: 220-120-9 REACH registration number: 01- 2120761540-60 INDEX-Number: 613-088-00-6 Acute Tox. 2 (Inhalation - dust) Acute Tox. 4 (oral) Skin Irrit. 2 Eye Dam. 1 Skin Sens. 1A Aquatic Acute 1 Aquatic Chronic 1 M-factor acute: 1 M-factor chronic: 1 H318, H315, H330, H302, H317, H400, H410 Specific concentration limit: Skin Sens. 1A: >= 0.036 % Acute toxicity estimate: oral: 450 mg/kg Inhalation: 0.21 mg/l

2-methylisothiazol-3(2H)-one

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Content (W/W): < 0.01 % CAS Number: 2682-20-4 EC-Number: 220-239-6 REACH registration number: 01- 2120764690-50 INDEX-Number: 613-326-00-9 Acute Tox. 2 (Inhalation - dust) Acute Tox. 3 (oral) Acute Tox. 3 (dermal) Skin Corr. 1B Eye Dam. 1 Skin Sens. 1A Aquatic Acute 1 Aquatic Chronic 1 M-factor acute: 10 M-factor chronic: 1 H330, H317, H314, H301 + H311, H400, H410 EUH071 Specific concentration limit: Skin Sens. 1A: >= 0.0015 %

Propane-1,2-diol Content (W/W): < 10 % CAS Number: 57-55-6 EC-Number: 200-338-0 REACH registration number: 01- 2119456809-23

For the classifications not written out in full in this section, including the hazard classes and the hazard statements, the full text is listed in section 16.

SECTION 4: First-Aid Measures

4.1. Description of first aid measures First aid personnel should pay attention to their own safety. If the patient is likely to become unconscious, place and transport in stable sideways position (recovery position). Immediately remove contaminated clothing.

If inhaled: Keep patient calm, remove to fresh air, seek medical attention.

On skin contact: Wash thoroughly with soap and water

On contact with eyes: Wash affected eyes for at least 15 minutes under running water with eyelids held open.

On ingestion: Immediately rinse mouth and then drink 200-300 ml of water, seek medical attention.

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4.2. Most important symptoms and effects, both acute and delayed Symptoms: Information, i.e. additional information on symptoms and effects may be included in the GHS labeling phrases available in Section 2 and in the Toxicological assessments available in Section 11., (Further) symptoms and / or effects are not known so far

Hazards: Information, i.e. additional information on symptoms and effects may be included in the GHS labeling phrases available in Section 2 and in the Toxicological assessments available in Section 11. (Further) symptoms and / or effects are not known so far

4.3. Indication of any immediate medical attention and special treatment needed Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote.

SECTION 5: Fire-Fighting Measures

5.1. Extinguishing media Suitable extinguishing media: water spray, carbon dioxide, foam, dry powder

5.2. Special hazards arising from the substance or mixture Endangering substances: Carbon monoxide, Carbon dioxide, Hydrochloric acid, Hydrogen fluoride, Hydrogen bromide, nitrogen oxides, halogenated compounds, sulfur oxides Advice: The substances/groups of substances mentioned can be released in case of fire.

5.3. Advice for fire-fighters Special protective equipment: Wear self-contained breathing apparatus and chemical-protective clothing.

Further information: In case of fire and/or explosion do not breathe fumes. Keep containers cool by spraying with water if exposed to fire. Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent systems. Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.

SECTION 6: Accidental Release Measures

6.1. Personal precautions, protective equipment and emergency procedures Use personal protective clothing. Avoid contact with the skin, eyes and clothing. Do not breathe vapour/spray.

6.2. Environmental precautions Do not discharge into the subsoil/soil. Do not discharge into drains/surface waters/groundwater.

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6.3. Methods and material for containment and cleaning up For small amounts: Pick up with suitable absorbent material (e.g. sand, sawdust, general-purpose binder, kieselguhr). For large amounts: Dike spillage. Pump off product. Dispose of absorbed material in accordance with regulations. Collect waste in suitable containers, which can be labeled and sealed. Clean contaminated floors and objects thoroughly with water and detergents, observing environmental regulations. Wear suitable protective equipment.

6.4. Reference to other sections Information regarding exposure controls/personal protection and disposal considerations can be found in section 8 and 13.

SECTION 7: Handling and Storage

7.1. Precautions for safe handling No special measures necessary if stored and handled correctly. Ensure thorough ventilation of stores and work areas. When using do not eat, drink or smoke. Hands and/or face should be washed before breaks and at the end of the shift.

Protection against fire and explosion: No special precautions necessary. The substance/product is non-combustible. Product is not explosive.

7.2. Conditions for safe storage, including any incompatibilities Segregate from foods and animal feeds. Further information on storage conditions: Keep away from heat. Protect from direct sunlight.

Storage stability: Storage duration: 24 Months

Protect from temperatures below:0 °C The product can crystallize below the limit temperature. Protect from temperatures above:40 °C Changes in the properties of the product may occur if substance/product is stored above indicated temperature for extended periods of time.

7.3. Specific end use(s) For the relevant identified use(s) listed in Section 1 the advice mentioned in this section 7 is to be observed.

Page: 9/22 BASF safety data sheet. This document has been drafted following generic rules for safety data sheets. It does not replace the safety data sheet provided according to Regulation (EC) No 1907/2006. Date / Revised: 13.09.2024 Version: 6.0 Date / Previous version: 29.07.2022 Previous version: 5.1 Product: Lexicon® Intrinsic Brand Fungicide (ID no. 30604404/SDS_CPA_EU/EN) Date of print 13.11.2024

SECTION 8: Exposure Controls/Personal Protection

8.1. Control parameters Components with occupational exposure limits 57-55-6: Propane-1,2-diol 175013-18-0: pyraclostrobin (ISO) TWA value 0.13 mg/m3 (BASF recomm. occupational exposure limit) 907204-31-3: Fluxapyroxad TWA value 0.5 mg/m3 (BASF recomm. occupational exposure limit)

8.2. Exposure controls Personal protective equipment Respiratory protection: Suitable respiratory protection for lower concentrations or short-term effect: Combination filter for gases/vapours of organic, inorganic, acid inorganic, alkaline compounds and toxic particles (e. g. EN 14387 Type ABEK-P3)

Hand protection: Suitable chemical resistant safety gloves (EN ISO 374-1) also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN ISO 374-1): E.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), butyl rubber (0.7 mm) etc.

Eye protection: Safety glasses with side-shields (frame goggles) (e.g. EN 166)

Body protection: Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of dust).

General safety and hygiene measures The statements on personal protective equipment in the instructions for use apply when handling crop-protection agents in final-consumer packing. Wearing of closed work clothing is recommended. Keep away from food, drink and animal feeding stuffs. Store work clothing separately.

SECTION 9: Physical and Chemical Properties

9.1. Information on basic physical and chemical properties State of matter: liquid Form: liquid Colour: off-white Odour: faint odour, fruity Odour threshold: Not determined due to potential health hazard by inhalation.

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crystallization temperature: approx. -5 °C (measured) Boiling point: approx. 100 °C (measured) Flammability: not applicable Lower explosion limit: As a result of our experience with this product and our knowledge of its composition we do not expect any hazard as long as the product is used appropriately and in accordance with the intended use. Upper explosion limit: As a result of our experience with this product and our knowledge of its composition we do not expect any hazard as long as the product is used appropriately and in accordance with the intended use. Flash point: No flash point - Measurement made up to the boiling point. Auto-ignition temperature: 535 °C (Directive 92/69/EEC, A.15) Thermal decomposition: 95 °C, 20 kJ/kg (DSC (OECD 113)) 165 °C, 140 kJ/kg (DSC (OECD 113)) 270 °C, 590 kJ/kg (DSC (OECD 113)) Not a substance liable to self-decomposition according to UN transport regulations, class 4.1. SADT: > 75 °C Heat accumulation / Dewar 500 ml (SADT, UN-Test H.4, 28.4.4) pH value: approx. 6 - 8 (20 °C) (measured with the undiluted substance) (pH Meter) Viscosity, dynamic: 63 mPa.s (20 °C, 100 1/s) (OECD Guideline 114) Solubility in water: dispersible Partitioning coefficient n-octanol/water (log Kow): not applicable Vapour pressure: approx. 23.4 hPa (approx. 20 °C) Information applies to the solvent. Density: approx. 1.16 g/cm3 (20 °C) (OECD Guideline 109) Relative vapour density (air): not applicable

9.2. Other information Information with regard to physical hazard classes Explosives Explosion hazard: not explosive (Directive 92/69/EEC, A.14)

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Oxidizing properties Fire promoting properties: not fire-propagating (Directive 2004/73/EC, A.21)

Other safety characteristics Evaporation rate: not applicable

SECTION 10: Stability and Reactivity

10.1. Reactivity No hazardous reactions if stored and handled as prescribed/indicated.

10.2. Chemical stability The product is stable if stored and handled as prescribed/indicated.

10.3. Possibility of hazardous reactions No hazardous reactions if stored and handled as prescribed/indicated.

10.4. Conditions to avoid See SDS section 7 - Handling and storage.

10.5. Incompatible materials Substances to avoid: strong acids, strong bases, strong oxidizing agents

10.6. Hazardous decomposition products Hazardous decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated.

SECTION 11: Toxicological Information

11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008 Acute toxicity Assessment of acute toxicity: Of moderate toxicity after single ingestion. Virtually nontoxic after a single skin contact. Virtually nontoxic by inhalation. The product has not been tested. The statement has been derived from substances/products of a similar structure or composition.

Experimental/calculated data: LD50 rat (oral): > 500 - < 2,000 mg/kg (OECD Guideline 423)

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LC50 rat (by inhalation): > 6.11 mg/l 4 h (OECD Guideline 403) An aerosol with respirable particles was tested. LD50 rat (dermal): > 5,000 mg/kg (OECD Guideline 402) No mortality was observed.

Irritation Assessment of irritating effects: Not irritating to eyes and skin. The product has not been tested. The statement has been derived from substances/products of a similar structure or composition.

Experimental/calculated data: Skin corrosion/irritation rabbit: non-irritant (OECD Guideline 404) Serious eye damage/irritation rabbit: non-irritant (OECD Guideline 405)

Respiratory/Skin sensitization Assessment of sensitization: Sensitization after skin contact possible. The product has not been tested. The statement has been derived from the properties of the individual components.

Information on: 2-Methyl-2H-isothiazol-3-one Experimental/calculated data: Buehler test guinea pig: skin sensitizing (OECD Guideline 406)

Germ cell mutagenicity Assessment of mutagenicity: The product has not been tested. The statement has been derived from the properties of the individual components.

Information on: bronopol (INN) Assessment of mutagenicity: The substance was not mutagenic in bacteria. The substance was mutagenic in various cell culture test systems; however, these results could not be confirmed in tests with mammals.

Carcinogenicity Assessment of carcinogenicity: The product has not been tested. The statement has been derived from the properties of the individual components.

Information on: Fluxapyroxad Assessment of carcinogenicity: Indication of possible carcinogenic effect in animal tests. The effect is caused by an animal specific mechanism that has no human counter part.

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Reproductive toxicity Assessment of reproduction toxicity: The product has not been tested. The statement has been derived from the properties of the individual components.

Information on: Fluxapyroxad Assessment of reproduction toxicity: The results of animal studies gave no indication of a fertility impairing effect. May cause harm to children via breast-feeding.

Developmental toxicity Assessment of teratogenicity: The product has not been tested. The statement has been derived from the properties of the individual components. Animal studies gave no indication of a developmental toxic effect at doses that were not toxic to the parental animals.

Specific target organ toxicity (single exposure) Assessment of STOT single: Causes temporary irritation of the respiratory tract.

Remarks: The product has not been tested. The statement has been derived from the properties of the individual components.

Repeated dose toxicity and Specific target organ toxicity (repeated exposure) Assessment of repeated dose toxicity: The product has not been tested. The statement has been derived from the properties of the individual components.

Information on: pyraclostrobin (ISO); methyl N-{2-[1-(4-chlorophenyl)-1H-pyrazol-3- yloxymethyl]phenyl}(N-methoxy)carbamate Assessment of repeated dose toxicity: Repeated exposure may affect certain organs. Target organs: Liver, gastrointestinal tract and nasal cavity

Information on: Fluxapyroxad Assessment of repeated dose toxicity: Adaptive effects were observed after repeated exposure in animal studies.

Information on: bronopol (INN) Assessment of repeated dose toxicity: After repeated exposure the prominent effect is local irritation.

Aspiration hazard not applicable

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Interactive effects No data available.

11.2. Information on other hazards Endocrine disrupting properties Product does not contain a substance above legal limits included in the list established in accordance with Article 59(1) of Regulation (EC) No 1907/2006 for having endocrine disrupting properties or is identified to have endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605.

Other information Other relevant toxicity information Misuse can be harmful to health.

SECTION 12: Ecological Information

12.1. Toxicity Assessment of aquatic toxicity: Very toxic to aquatic life with long lasting effects. The product has not been tested. The statement has been derived from the properties of the individual components.

Information on:pyraclostrobin (ISO); methyl N-{2-[1-(4-chlorophenyl)-1H-pyrazol-3- yloxymethyl]phenyl}(N-methoxy)carbamate Toxicity to fish: LC50 (96 h) 0.00616 mg/l, Oncorhynchus mykiss (EPA 72-1, Flow through.)

Information on:Fluxapyroxad Toxicity to fish: LC50 (96 h) 0.29 mg/l, Cyprinus carpio (Fish test acute, semistatic) LC50 (96 h) 0.546 mg/l, Oncorhynchus mykiss (OECD Guideline 203, static) LC50 (96 h) 1.15 mg/l, Lepomis macrochirus (OECD Guideline 203, static) LC50 (96 h) 0.466 mg/l, Pimephales promelas (OECD Guideline 203, static)

Information on:pyraclostrobin (ISO); methyl N-{2-[1-(4-chlorophenyl)-1H-pyrazol-3- yloxymethyl]phenyl}(N-methoxy)carbamate Aquatic invertebrates: EC50 (48 h) 0.0157 mg/l, Daphnia magna (OECD Guideline 202, part 1, static)

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EC50 (96 h) 0.00416 mg/l, Americamysis bahia

Information on:Fluxapyroxad Aquatic invertebrates: EC50 (48 h) 6.78 mg/l, Daphnia magna (OECD Guideline 202, part 1, static)

Information on:pyraclostrobin (ISO); methyl N-{2-[1-(4-chlorophenyl)-1H-pyrazol-3- yloxymethyl]phenyl}(N-methoxy)carbamate Aquatic plants: EC10 (7 d) 0.82 mg/l (growth rate), Lemna gibba EC50 (7 d) > 1.007 mg/l (growth rate), Lemna gibba EC50 (72 h) 0.011 mg/l (growth rate), Navicula pelliculosa

Information on:Fluxapyroxad Aquatic plants: EC50 (72 h) 0.70 mg/l (growth rate), Pseudokirchneriella subcapitata (OECD Guideline 201) EC50 (96 h) 0.66 mg/l (growth rate), Pseudokirchneriella subcapitata EC10 (72 h) 0.31 mg/l (growth rate), Pseudokirchneriella subcapitata EC10 (96 h) 0.36 mg/l (growth rate), Pseudokirchneriella subcapitata

Information on:Fluxapyroxad Chronic toxicity to fish: No observed effect concentration (33 d) 0.0359 mg/l, Pimephales promelas (OECD Guideline 210, Flow through.)

Information on:pyraclostrobin (ISO); methyl N-{2-[1-(4-chlorophenyl)-1H-pyrazol-3- yloxymethyl]phenyl}(N-methoxy)carbamate Chronic toxicity to fish: No observed effect concentration (98 d) approx. 0.00235 mg/l, Oncorhynchus mykiss (OECD Guideline 210, Flow through.)

Information on:Fluxapyroxad Chronic toxicity to aquatic invertebrates: No observed effect concentration (21 d) 0.5 mg/l, Daphnia magna (OECD Guideline 211, semistatic)

Information on:pyraclostrobin (ISO); methyl N-{2-[1-(4-chlorophenyl)-1H-pyrazol-3- yloxymethyl]phenyl}(N-methoxy)carbamate Chronic toxicity to aquatic invertebrates: No observed effect concentration (21 d) 0.004 mg/l, Daphnia magna (OECD Guideline 202, part 2, semistatic) The details of the toxic effect relate to the nominal concentration.

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No observed effect concentration (31 d) 0.000365 mg/l, Mysidopsis bahia

12.2. Persistence and degradability Assessment biodegradation and elimination (H2O): The product has not been tested. The statement has been derived from the properties of the individual components.

Information on:pyraclostrobin (ISO); methyl N-{2-[1-(4-chlorophenyl)-1H-pyrazol-3- yloxymethyl]phenyl}(N-methoxy)carbamate Assessment biodegradation and elimination (H2O): Not readily biodegradable (by OECD criteria).

Information on:Fluxapyroxad Assessment biodegradation and elimination (H2O): Not readily biodegradable (by OECD criteria).

12.3. Bioaccumulative potential Assessment bioaccumulation potential: The product has not been tested. The statement has been derived from the properties of the individual components.

Information on:pyraclostrobin (ISO); methyl N-{2-[1-(4-chlorophenyl)-1H-pyrazol-3- yloxymethyl]phenyl}(N-methoxy)carbamate Bioaccumulation potential: Bioconcentration factor(BCF): 379 - 507, Oncorhynchus mykiss (OECD Guideline 305) Accumulation in organisms is not to be expected.

Information on:Fluxapyroxad Bioaccumulation potential: Bioconcentration factor(BCF): 36 - 37 (28 d), Lepomis macrochirus (OECD Guideline 305) Does not accumulate in organisms.

12.4. Mobility in soil Assessment transport between environmental compartments: Adsorption in soil: The product has not been tested. The statement has been derived from the properties of the individual components.

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Information on:pyraclostrobin (ISO); methyl N-{2-[1-(4-chlorophenyl)-1H-pyrazol-3- yloxymethyl]phenyl}(N-methoxy)carbamate Assessment transport between environmental compartments: Adsorption in soil: Following exposure to soil, adsorption to solid soil particles is probable, therefore contamination of groundwater is not expected.

Information on:Fluxapyroxad Assessment transport between environmental compartments: Adsorption in soil: Following exposure to soil, adsorption to solid soil particles is probable, therefore contamination of groundwater is not expected.

12.5. Results of PBT and vPvB assessment The product does not contain a substance fulfilling the PBT (persistent/bioaccumulative/toxic) criteria or the vPvB (very persistent/very bioaccumulative) criteria.

12.6. Endocrine disrupting properties Product does not contain a substance above legal limits included in the list established in accordance with Article 59(1) of Regulation (EC) No 1907/2006 for having endocrine disrupting properties or is identified to have endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605.

12.7. Other adverse effects The product does not contain substances that are listed in Regulation (EC) 1005/2009 on substances that deplete the ozone layer.

Additional information Other ecotoxicological advice: Do not discharge product into the environment without control.

SECTION 13: Disposal Considerations

13.1. Waste treatment methods Must be sent to a suitable incineration plant, observing local regulations.

Contaminated packaging: Contaminated packaging should be emptied as far as possible and disposed of in the same manner as the substance/product.

SECTION 14: Transport Information

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Land transport ADR UN number or ID number: UN3082 UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (PYRACLOSTROBIN, FLUXAPYROXAD) Transport hazard class(es): 9, EHSM Packing group: III Environmental hazards: yes Special precautions for user: None known

RID UN number or ID number: UN3082 UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (PYRACLOSTROBIN, FLUXAPYROXAD) Transport hazard class(es): 9, EHSM Packing group: III Environmental hazards: yes Special precautions for user: None known

Inland waterway transport ADN UN number or ID number: UN3082 UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (PYRACLOSTROBIN, FLUXAPYROXAD) Transport hazard class(es): 9, EHSM Packing group: III Environmental hazards: yes Special precautions for user: None known

Transport in inland waterway vessel Not evaluated

Sea transport IMDG UN number or ID number: UN 3082

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UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (PYRACLOSTROBIN, FLUXAPYROXAD) Transport hazard class(es): 9, EHSM Packing group: III Environmental hazards: yes Marine pollutant: YES Special precautions for user: EmS: F-A; S-F

Air transport IATA/ICAO UN number or ID number: UN 3082 UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (PYRACLOSTROBIN, FLUXAPYROXAD) Transport hazard class(es): 9, EHSM Packing group: III Environmental hazards: yes Special precautions for user: None known

14.1. UN number or ID number See corresponding entries for “UN number or ID number” for the respective regulations in the tables above.

14.2. UN proper shipping name See corresponding entries for “UN proper shipping name” for the respective regulations in the tables above.

14.3. Transport hazard class(es) See corresponding entries for “Transport hazard class(es)” for the respective regulations in the tables above.

14.4. Packing group See corresponding entries for “Packing group” for the respective regulations in the tables above.

14.5. Environmental hazards See corresponding entries for “Environmental hazards” for the respective regulations in the tables above.

14.6. Special precautions for user See corresponding entries for “Special precautions for user” for the respective regulations in the tables above.

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14.7. Maritime transport in bulk according to IMO instruments Maritime transport in bulk is not intended.

Further information Product may be shipped as non-hazardous in suitable packages containing a net quantity of 5 L or less under the provisions of various regulatory agencies: ADR, RID, ADN: Special Provision 375; IMDG: 2.10.2.7; IATA: A197; TDG: Special Provision 99(2); 49CFR: §171.4 (c) (2) and also the Special Provision 375 in Appendix B which is regulated in China "Regulations Concerning Road Transportation of Dangerous Goods Part 3: Index of dangerous goods name and transportation requirements" (JT/T 617.3)

SECTION 15: Regulatory Information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture Prohibitions, Restrictions and Authorizations Annex XVII of Regulation (EC) No 1907/2006: Number on List: 3, 75

Restrictions of Regulation (EC) No 1907/2006, Annex XVII, do not apply for the intended use(s) of the product given in this SDS.

Directive 2012/18/EU - Control of Major Accident Hazards involving dangerous substances (EU): List entry in regulation: E1 Classification applies for standard conditions of temperature and pressure.

To avoid risks to man and the environment, comply with the instructions for use.

15.2. Chemical Safety Assessment Advice on product handling can be found in sections 7 and 8 of this safety data sheet.

SECTION 16: Other Information

For proper and safe use of this product, please refer to the approval conditions laid down on the product label.

Full text of the classifications, including the hazard classes and the hazard statements, if mentioned in section 2 or 3: Acute Tox. Acute toxicity Skin Sens. Skin sensitization Repr. Reproductive toxicity STOT SE Specific target organ toxicity — single exposure STOT RE Specific target organ toxicity — repeated exposure Aquatic Acute Hazardous to the aquatic environment - acute Aquatic Chronic Hazardous to the aquatic environment - chronic

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Skin Irrit. Skin irritation Eye Dam./Irrit. Serious eye damage/eye irritation Eye Dam. Serious eye damage Skin Corr. Skin corrosion H302 Harmful if swallowed. H317 May cause an allergic skin reaction. H373 May cause damage to organs through prolonged or repeated exposure. H362 May cause harm to breast-fed children. H335 May cause respiratory irritation. H361d Suspected of damaging the unborn child. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. EUH401 To avoid risks to human health and the environment, comply with the instructions for use. H315 Causes skin irritation. H331 Toxic if inhaled. H373 May cause damage to organs (Liver, Nasal cavity, Gastrointestinal tract) through prolonged or repeated exposure. H319 Causes serious eye irritation. H412 Harmful to aquatic life with long lasting effects. H318 Causes serious eye damage. H312 Harmful in contact with skin. H301 + H331 Toxic if swallowed or if inhaled. H330 Fatal if inhaled. H314 Causes severe skin burns and eye damage. H301 + H311 Toxic if swallowed or in contact with skin. EUH071 Corrosive to the respiratory tract.

Abbreviations ADR = The European Agreement concerning the International Carriage of Dangerous Goods by Road. ADN = The European Agreement concerning the International Carriage of Dangerous Goods by Inland waterways. ATE = Acute Toxicity Estimates. CAO = Cargo Aircraft Only. CAS = Chemical Abstract Service. CLP = Classification, Labelling and Packaging of substances and mixtures. DIN = German national organization for standardization. DNEL = Derived No Effect Level. EC50 = Effective concentration median for 50% of the population. EC = European Community. EN = European Standards. IARC = International Agency for Research on Cancer. IATA = International Air Transport Association. IBC-Code = Intermediate Bulk Container code. IMDG = International Maritime Dangerous Goods Code. ISO = International Organization for Standardization. STEL = Short-Term Exposure Limit. LC50 = Lethal concentration median for 50% of the population. LD50 = Lethal dose median for 50% of the population. TLV = Threshold Limit Value. MARPOL = The International Convention for the Prevention of Pollution from Ships. NEN = Dutch Norm. NOEC = No Observed Effect Concentration. OEL = Occupational Exposure Limit. OECD = Organization for Economic Cooperation and Development. PBT = Persistent, Bioaccumulative and Toxic. PNEC = Predicted No Effect Level. PPM = Parts per million. RID = The European Agreement concerning the International Carriage of Dangerous Goods by Rail. TWA = Time Weight Average. UN-number = UN number at transport. vPvB = very Persistent and very Bioaccumulative.

The data contained in this safety data sheet are based on our current knowledge and experience and describe the product only with regard to safety requirements. This safety data sheet is neither a Certificate of Analysis (CoA) nor technical data sheet and shall not be mistaken for a specification

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agreement. Identified uses in this safety data sheet do neither represent an agreement on the corresponding contractual quality of the substance/mixture nor a contractually designated use. It is the responsibility of the recipient of the product to ensure any proprietary rights and existing laws and legislation are observed.

Vertical lines in the left hand margin indicate an amendment from the previous version.