SDS - Envu Indemnify Turf Nematicide - 230404

SAFETY DATA SHEET INDEMNIFY TURF NEMATICIDE

Version 1.0 Revision Date: 04.04.2023 SDS Number: 11187422-00001 Date of last issue: - Date of first issue: 04.04.2023 1 / 15

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Product name : INDEMNIFY TURF NEMATICIDE Product code : Article/SKU: 86754355, 86720930 UVP: 80978235 Specification: 102000026892

Manufacturer or supplier's details Company : 2022 Environmental Science AU Pty Ltd

Address : Suite 2.06, Level 2, 737 Burwood Road Hawthorn East, Australia 3123 Emergency telephone number :

Recommended use of the chemical and restrictions on use Recommended use : Nematicide Fungicide Restrictions on use : Not applicable

SECTION 2. HAZARDS IDENTIFICATION

GHS Classification Not a hazardous substance or mixture.

GHS label elements No hazard pictogram, no signal word, no hazard statement(s), no precautionary statement(s) required

Other hazards which do not result in classification Vapours may form explosive mixture with air.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture : Mixture

Components

SECTION 4. FIRST AID MEASURES

If inhaled : If inhaled, remove to fresh air. Get medical attention if symptoms occur. In case of skin contact : Wash with water and soap as a precaution. Get medical attention if symptoms occur. In case of eye contact : Flush eyes with water as a precaution. Get medical attention if irritation develops and persists. If swallowed : If swallowed, DO NOT induce vomiting. Get medical attention if symptoms occur. Rinse mouth thoroughly with water. Most important symptoms and effects, both acute and delayed : No symptoms known or expected. Protection of first-aiders : No special precautions are necessary for first aid responders. Notes to physician : Treat symptomatically and supportively. There is no specific antidote available.

SECTION 5. FIREFIGHTING MEASURES

Suitable extinguishing media : Water spray Alcohol-resistant foam Carbon dioxide (CO2) Dry chemical Unsuitable extinguishing media : High volume water jet Specific hazards during firefighting : Do not use a solid water stream as it may scatter and spread fire. Flash back possible over considerable distance. Vapours may form explosive mixtures with air. Exposure to combustion products may be a hazard to health. Hazardous combustion products : Carbon oxides Chlorine compounds Fluorine compounds Nitrogen oxides (NOx) Specific extinguishing methods : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Use water spray to cool unopened containers. Remove undamaged containers from fire area if it is safe to do so. Evacuate area. Special protective equipment for firefighters : Wear self-contained breathing apparatus for firefighting if necessary. Use personal protective equipment.

Hazchem Code : •3Z

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures : Remove all sources of ignition. Follow safe handling advice (see section 7) and personal protective equipment recommendations (see section 8). Environmental precautions : Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Prevent spreading over a wide area (e.g. by containment or oil barriers). Retain and dispose of contaminated wash water. Local authorities should be advised if significant spillages cannot be contained. Methods and materials for containment and cleaning up : Non-sparking tools should be used. Soak up with inert absorbent material. Suppress (knock down) gases/vapours/mists with a water spray jet. For large spills, provide dyking or other appropriate containment to keep material from spreading. If dyked material can be pumped, store recovered material in appropriate container. Clean up remaining materials from spill with suitable absorbent. Local or national regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which regulations are applicable. Sections 13 and 15 of this SDS provide information regarding certain local or national requirements.

SECTION 7. HANDLING AND STORAGE

Technical measures : See Engineering measures under EXPOSURE CONTROLS/PERSONAL PROTECTION section. Local/Total ventilation : If sufficient ventilation is unavailable, use with local exhaust ventilation. Advice on safe handling : Avoid prolonged or repeated contact with skin. Handle in accordance with good industrial hygiene and safety practice, based on the results of the workplace exposure assessment Keep container tightly closed. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Take precautionary measures against static discharges. Take care to prevent spills, waste and minimize release to the environment. Hygiene measures : If exposure to chemical is likely during typical use, provide eye flushing systems and safety showers close to the working place. When using do not eat, drink or smoke. Wash contaminated clothing before re-use. Conditions for safe storage : Keep in properly labelled containers. Keep tightly closed. Keep in a cool, well-ventilated place. Store in accordance with the particular national regulations. Keep away from heat and sources of ignition. Materials to avoid : Do not store with the following product types: Strong oxidizing agents

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

Engineering measures : Ensure adequate ventilation, especially in confined areas. Minimize workplace exposure concentrations.

Personal protective equipment Respiratory protection : If adequate local exhaust ventilation is not available or exposure assessment demonstrates exposures outside the recommended guidelines, use respiratory protection. Filter type : Particulates type Hand protection Material : Nitrile rubber Break through time : 480 min Glove thickness : 0.4 mm Protective index : Class 6 Remarks : Choose gloves to protect hands against chemicals depending on the concentration and quantity of the hazardous substance and specific to place of work. For special applications, we recommend clarifying the resistance to chemicals of the aforementioned protective gloves with the glove manufacturer. Wash hands before breaks and at the end of workday. Eye protection : Wear the following personal protective equipment: Safety glasses Skin and body protection : Select appropriate protective clothing based on chemical resistance data and an assessment of the local exposure potential. Wear the following personal protective equipment: If assessment demonstrates that there is a risk of explosive atmospheres or flash fires, use flame retardant antistatic protective clothing. Skin contact must be avoided by using impervious protective clothing (gloves, aprons, boots, etc).

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : suspension Colour : white, beige Odour : characteristic Odour Threshold : No data available pH : 5.5 - 8 (23 °C) Concentration: 100 % Melting point/freezing point : No data available Initial boiling point and boiling range : No data available Flash point : > 85 °C Decomposition Evaporation rate : No data available Flammability (solid, gas) : Not applicable Not applicable Flammability (liquids) : Does not sustain combustion. No data available Self-ignition : 430 °C Upper explosion limit / Upper flammability limit : No data available Lower explosion limit / Lower flammability limit : No data available Vapour pressure : No data available Relative vapour density : No data available Relative density : No data available Density : ca. 1.16 g/cm³ (20 °C) Solubility(ies) Water solubility : dispersible Partition coefficient: n-octanol/water : Not applicable Auto-ignition temperature : No data available Decomposition temperature : No data available Viscosity Viscosity, dynamic : 300 - 450 mPa.s Shear rate of 20/sec Viscosity, kinematic : No data available Explosive properties : Not explosive Method: OECD Test Guideline 113 Oxidizing properties : The substance or mixture is not classified as oxidizing. Particle size : 3 - 6 µm

SECTION 10. STABILITY AND REACTIVITY

Reactivity : Not classified as a reactivity hazard. Chemical stability : Stable under normal conditions. Possibility of hazardous reactions : Combustible liquid. Vapours may form explosive mixture with air. Can react with strong oxidizing agents. Conditions to avoid : Heat, flames and sparks. Incompatible materials : Oxidizing agents Hazardous decomposition products : No hazardous decomposition products are known.

SECTION 11. TOXICOLOGICAL INFORMATION

Exposure routes : Inhalation Skin contact Ingestion Eye contact

Acute toxicity Not classified based on available information.

Components: Propylene glycol: Acute oral toxicity : LD50 (Rat): 22,000 mg/kg Acute inhalation toxicity : LC50 (Rat): > 44.9 mg/l Exposure time: 4 h Test atmosphere: dust/mist Acute dermal toxicity : LD50 (Rabbit): > 2,000 mg/kg Assessment: The substance or mixture has no acute dermal toxicity

2,4,7,9-Tetramethyl-5-decyne-4,7-diol ethoxylate: Acute oral toxicity : LD50 (Rat, male): > 5,000 mg/kg Remarks: Based on data from similar materials Acute dermal toxicity : LD50 (Rat): > 2,000 mg/kg Method: OECD Test Guideline 402 Remarks: Based on data from similar materials

Skin corrosion/irritation Not classified based on available information.

Components: Propylene glycol: Species : Rabbit Method : OECD Test Guideline 404 Result : No skin irritation

2,4,7,9-Tetramethyl-5-decyne-4,7-diol ethoxylate: Species : Rabbit Result : No skin irritation Remarks : Based on data from similar materials

Serious eye damage/eye irritation Not classified based on available information.

Components: Propylene glycol: Species : Rabbit Result : No eye irritation Method : OECD Test Guideline 405

2,4,7,9-Tetramethyl-5-decyne-4,7-diol ethoxylate: Species : Rabbit Result : Irreversible effects on the eye Remarks : Based on data from similar materials

Respiratory or skin sensitisation Skin sensitisation Not classified based on available information. Respiratory sensitisation Not classified based on available information.

Components: Propylene glycol: Test Type : Maximisation Test Exposure routes : Skin contact Species : Guinea pig Result : negative

2,4,7,9-Tetramethyl-5-decyne-4,7-diol ethoxylate: Test Type : Local lymph node assay (LLNA) Exposure routes : Skin contact Species : Mouse Method : OECD Test Guideline 429 Result : positive Remarks : Based on data from similar materials Assessment : Probability or evidence of low to moderate skin sensitisation rate in humans

Chronic toxicity Germ cell mutagenicity Not classified based on available information.

Components: Propylene glycol: Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES) Result: negative Test Type: Chromosome aberration test in vitro Method: OECD Test Guideline 473 Result: negative Genotoxicity in vivo : Test Type: Mammalian erythrocyte micronucleus test (in vivo cytogenetic assay) Species: Mouse Application Route: Intraperitoneal injection Result: negative

2,4,7,9-Tetramethyl-5-decyne-4,7-diol ethoxylate: Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES) Method: OECD Test Guideline 471 Result: negative Test Type: In vitro mammalian cell gene mutation test Method: OECD Test Guideline 476 Result: negative Remarks: Based on data from similar materials Test Type: Chromosome aberration test in vitro Method: OECD Test Guideline 473 Result: negative

Carcinogenicity Not classified based on available information.

Components: Propylene glycol: Species : Rat Application Route : Ingestion Exposure time : 2 Years Result : negative

Reproductive toxicity Not classified based on available information.

Components: Propylene glycol: Effects on fertility : Test Type: Two-generation reproduction toxicity study Species: Mouse Application Route: Ingestion Result: negative Effects on foetal development : Test Type: Embryo-foetal development Species: Mouse Application Route: Ingestion Result: negative

2,4,7,9-Tetramethyl-5-decyne-4,7-diol ethoxylate: Effects on fertility : Test Type: Combined repeated dose toxicity study with the reproduction/developmental toxicity screening test Species: Rat Application Route: Ingestion Method: OECD Test Guideline 422 Result: negative Effects on foetal development : Test Type: Combined repeated dose toxicity study with the reproduction/developmental toxicity screening test Species: Rat Application Route: Ingestion Method: OECD Test Guideline 422 Result: negative

STOT - single exposure Not classified based on available information.

STOT - repeated exposure Not classified based on available information.

Repeated dose toxicity

Components: Propylene glycol: Species : Rat, male NOAEL : >= 1,700 mg/kg Application Route : Ingestion Exposure time : 2 yr

2,4,7,9-Tetramethyl-5-decyne-4,7-diol ethoxylate: Species : Rat, male NOAEL : 184 mg/kg LOAEL : 539 mg/kg Application Route : Ingestion Exposure time : 28 Days Method : OECD Test Guideline 422

Aspiration toxicity Not classified based on available information.

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity

Components: Propylene glycol: Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 40,613 mg/l Exposure time: 96 h Toxicity to daphnia and other aquatic invertebrates : EC50 (Ceriodaphnia dubia (water flea)): 18,340 mg/l Exposure time: 48 h Toxicity to algae/aquatic plants : ErC50 (Skeletonema costatum (marine diatom)): 19,300 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC (Ceriodaphnia dubia (water flea)): 13,020 mg/l Exposure time: 7 d Toxicity to microorganisms : NOEC (Pseudomonas putida): > 20,000 mg/l Exposure time: 18 h

2,4,7,9-Tetramethyl-5-decyne-4,7-diol ethoxylate: Toxicity to fish : LC50 (Scophthalmus maximus (turbot)): > 10 - 100 mg/l Exposure time: 96 h Method: OECD Test Guideline 203 Toxicity to daphnia and other aquatic invertebrates : EC50 (Acartia tonsa (Calanoid copepod)): > 100 mg/l Exposure time: 48 h Remarks: Based on data from similar materials Toxicity to algae/aquatic plants : ErC50 (Raphidocelis subcapitata (freshwater green alga)): > 10 - 100 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 Remarks: Based on data from similar materials EC10 (Raphidocelis subcapitata (freshwater green alga)): > 1 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 Remarks: Based on data from similar materials

Persistence and degradability

Components: Propylene glycol: Biodegradability : Result: Readily biodegradable. Biodegradation: 98.3 % Exposure time: 28 d Method: OECD Test Guideline 301F

2,4,7,9-Tetramethyl-5-decyne-4,7-diol ethoxylate: Biodegradability : Result: Not readily biodegradable. Remarks: Based on data from similar materials

Bioaccumulative potential

Components: Propylene glycol: Partition coefficient: n-octanol/water : log Pow: -1.07 Method: Regulation (EC) No. 440/2008, Annex, A.8

2,4,7,9-Tetramethyl-5-decyne-4,7-diol ethoxylate: Partition coefficient: n-octanol/water : log Pow: > 1.8 - < 2.5 Method: Regulation (EC) No. 440/2008, Annex, A.8

Mobility in soil No data available

Other adverse effects No data available

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods Waste from residues : It is best to use all of the product in accordance with label directions. If it is necessary to dispose of unused product, please follow container label instructions and applicable local guidelines. Do not dispose of waste into sewer. Contaminated packaging : Follow advice on product label and/or leaflet. Empty containers retain residue and can be dangerous. Do not re-use empty containers.

SECTION 14. TRANSPORT INFORMATION

International Regulations

UNRTDG UN number : UN 3082 Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Fluopyram, Reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H-isothiazol-3-one [EC no. 220-239-6] (3:1)) Class : 9 Packing group : III Labels : 9

IATA-DGR UN/ID No. : UN 3082 Proper shipping name : Environmentally hazardous substance, liquid, n.o.s. (Fluopyram, Reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H-isothiazol-3-one [EC no. 220-239-6] (3:1)) Class : 9 Packing group : III Labels : Miscellaneous Packing instruction (cargo aircraft) : 964 Packing instruction (passenger aircraft) : 964 Environmentally hazardous : yes

IMDG-Code UN number : UN 3082 Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Fluopyram, Reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H-isothiazol-3-one [EC no. 220-239-6] (3:1)) Class : 9 Packing group : III Labels : 9 EmS Code : F-A, S-F Marine pollutant : yes

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied.

National Regulations

ADG UN number : UN 3082 Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Fluopyram, Reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H-isothiazol-3-one [EC no. 220-239-6] (3:1)) Class : 9 Packing group : III Labels : 9 Hazchem Code : •3Z

Special precautions for user The transport classification(s) provided herein are for informational purposes only, and solely based upon the properties of the unpackaged material as it is described within this Safety Data Sheet. Transportation classifications may vary by mode of transportation, package sizes, and variations in regional or country regulations.

SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture Standard for the Uniform Scheduling of Medicines and Poisons : No poison schedule number allocated Prohibition/Licensing Requirements : There is no applicable prohibition, authorisation and restricted use requirements, including for carcinogens referred to in Schedule 10 of the model WHS Act and Regulations.

Regulation (EU) No 528/2012 of the European Parliament and of the Council of 22 May 2012 concerning the making available on the market and use of biocidal products Authorisation number : 84365 Product Type : Insecticides, acaricides and products to control other arthropods Active substance : 400 g/l Fluopyram

SECTION 16. OTHER INFORMATION

Further information Revision Date : 04.04.2023 Sources of key data used to compile the Safety Data Sheet : Internal technical data, data from raw material SDSs, OECD eChem Portal search results and European Chemicals Agency, Date format : dd.mm.yyyy

Full text of other abbreviations AU OEL : Australia. Workplace Exposure Standards for Airborne Contaminants. AU OEL / TWA : Exposure standard - time weighted average

AIIC - Australian Inventory of Industrial Chemicals; ANTT - National Agency for Transport by Land of Brazil; ASTM - American Society for the Testing of Materials; bw - Body weight; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the German Institute for Standardisation; DSL - Domestic Substances List (Canada); ECx - Concentration associated with x% response; ELx - Loading rate associated with x% response; EmS - Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized System; GLP - Good Laboratory Practice; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; IBC - International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO - International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50 - Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - International Convention for the Prevention of Pollution from Ships; n.o.s. - Not Otherwise Specified; Nch - Chilean Norm; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NOM - Official Mexican Norm; NTP - National Toxicology Program; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure Activity Relationship; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals; SADT - Self-Accelerating Decomposition Temperature; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TDG - Transportation of Dangerous Goods; TECI - Thailand Existing Chemicals Inventory; TSCA - Toxic Substances Control Act (United States); UN - United Nations; UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods; vPvB - Very Persistent and Very Bioaccumulative; WHMIS - Workplace Hazardous Materials Information System

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and shall not be considered a warranty or quality specification of any type. The information provided relates only to the specific material identified at the top of this SDS and may not be valid when the SDS material is used in combination with any other materials or in any process, unless specified in the text. Material users should review the information and recommendations in the specific context of their intended manner of handling, use, processing and storage, including an assessment of the appropriateness of the SDS material in the user’s end product, if applicable.

AU / EN